赣西浒坑钨矿床成矿岩体的磷灰石和锆石微量元素特征及其对成岩成矿的指示

doi:10.11872/j.issn.1005-2518.2022.06.074

Abstract

Abstract:

The South China Block is an important polymetallic metallogenic area mainly related to the W，Sn，Cu and other metals，most of that mineralization is closely related to the Mesozoic magmatism.Based on the analysis of zircon U-Pb dating and trace element of apatite and zircon of the muscovite granite related to mineralization in the Hukeng tungsten deposit，the age，magmatic properties and evolution characteristics of the metallogenic rock was constraint in this study.The results show that the muscovite granite was formed at （152.3±1.73）Ma，which is consistent with the peak period of polymetallic mineralization in South China（170~150 Ma）.In addition，trace element of apatite shows that it has a M-shaped REE chondrite normalized pattern，with features of enrich in F［w（F） is 3.52%~4.09%）］and Mn（5 081×10^-6~13 948×10^-6），and depleted in Cl［w（Cl）<0.012%］ and Mg（5.91×10^-6~24.08×10^-6），which are consistent with that in the high fractionated S-type granite.Besides，trace element of zircon shows that it has high Th/U ratio，LREE-depleted and HREE-enriched REE chondrite normalized pattern.Furthermore，the oxidized state and temperature of the rock were constraint by Ce，U and Ti content in zircon，which shows that zircon was crystallized at the conditions of high temperature（800 ℃） and low oxygen fugacity in the early period of magma.Combined with previous studies，it is concluded that the Hukeng granite experienced strong early fractional crystallization and the formation of the Hukeng deposit may be related to the evolution of reductive highly fractionated magmas.

Key words: zircon, apatite, U-Pb dating, trace element, ore-forming magma, Hukeng tungsten deposit

CLC Number:

P618.67

Hua WANG,Shaohao ZOU,Long CHEN,Deru XU,Xilian CHEN,Xuena WANG,Haodong FENG. Trace Element Characteristics of Zircon and Apatite Metallogenic in Rocks of Hukeng Tungsten Deposit in Western Jiangxi Province：Implications for Petrogenesis and Mineralization[J].Gold Science and Technology, 2022, 30(6): 848-865.

Figures/Tables 13

Fig.1

Fig.2

Fig.3

Fig.4

Table 1

Fig.5

Table 2

LA-ICP-MS trace element analysis results of the zircon grains from muscovite granite in Hukeng tungsten deposit（×10-6）"

测点编号	Ti	T/℃	Y	Nb	La	Ce	Pr	Nd	Sm	Eu	Gd	Tb	Dy	Ho	Er	Tm	Yb	Lu	Hf	Ta	U	Th	Pb
21HK01-4-1	-		1 225	36.19	-	43.99	-	2.59	6.45	0.92	28.27	9.02	112.14	36.56	158.20	37.34	342	68.86	10 643	9.35	281.2	265.5	27.08
21HK01-4-2	9.28	807.28	1 700	6.67	-	35.36	0.29	2.98	6.72	2.28	39.69	12.70	158.10	57.20	242.38	54.62	485	93.70	9 550	1.29	253.0	212.6	23.92
21HK01-4-3	8.24	794.79	807	3.60	-	22.69	-	1.63	2.86	0.96	19.12	6.08	70.32	26.71	116.98	26.20	247	51.57	10 519	2.64	142.1	74.9	14.57
21HK01-4-4	-		1 032	6.35	-	44.99	-	1.11	3.34	0.88	20.21	6.64	90.83	35.42	149.87	34.93	332	64.55	10 286	2.13	271.5	212.6	27.30
21HK01-4-5	-		1 065	3.36	-	27.08	0.16	1.91	5.21	1.54	21.76	7.73	98.99	36.64	154.52	34.64	310	61.02	9 816	1.04	235.5	130.3	25.86
21HK01-4-6	-		863	4.64	-	20.99	-	-	2.72	1.33	22.91	6.13	79.88	27.61	114.23	29.36	255	54.64	8 904	0.99	185.9	93.7	41.35
21HK01-4-7	-		1 307	10.63	-	46.54	-	1.42	3.41	1.07	26.29	9.26	112.42	45.94	192.03	45.64	413	81.10	10 967	3.58	334.4	236.2	33.74
21HK01-4-8	11.22	827.69	2 691	10.77	1.46	65.36	0.63	4.57	8.59	3.25	50.02	18.31	230.60	89.99	383.85	90.28	822	160.23	9 412	2.91	416.4	318.1	38.37
21HK01-4-9	-		2 790	8.36	-	47.41	0.47	7.01	13.95	4.25	69.63	22.92	267.88	96.59	386.72	88.29	795	152.73	10 166	2.46	787.8	491.5	83.15
21HK01-4-10	20.77	899.57	1 156	19.09	-	2.62	0.19	2.60	5.60	0.34	24.61	8.24	93.97	39.86	180.75	45.11	400	81.04	9 930	2.09	279.9	82.2	75.27
21HK01-4-11	-		1 385	6.69	-	46.73	-	1.25	4.50	1.52	28.62	9.19	123.50	46.14	193.65	48.47	438	85.10	11 193	2.49	350.6	240.6	35.74
21HK01-4-12	-		1 558	4.14	-	4.68	-	2.33	3.85	0.28	26.66	9.83	137.76	53.43	247.93	57.60	528	99.38	11 360	1.28	404.6	184.3	110.04
21HK01-4-13	-		3 073	12.68	-	67.62	0.61	9.45	14.53	4.50	90.64	26.07	306.41	106.84	424.27	91.79	797	145.47	10 277	2.84	458.9	491.2	46.61
21HK01-4-14	14.53	856.76	1 154	3.43	0.26	20.20	0.40	3.23	5.70	2.02	33.75	9.63	111.07	40.14	163.40	34.89	315	58.33	9 197	1.21	128.5	86.3	13.02
21HK01-4-15	-		2 243	35.30	0.30	58.29	-	2.46	6.32	0.95	40.47	15.78	205.67	75.45	321.37	75.60	656	120.08	12 508	8.81	643.6	476.3	62.69
21HK01-4-16	-		1 272	7.24	-	29.11	-	1.27	4.08	0.71	27.67	8.33	113.95	42.95	187.71	43.08	386	73.47	11 174	2.95	403.7	187.1	41.10
21HK01-4-17	-		3 340	88.86	0.49	46.58	0.51	2.66	10.39	1.31	59.68	21.57	284.47	107.66	466.49	114.06	1108	207.89	14 774	19.98	2817.8	717.6	274.37
21HK01-4-18	-		640	2.41	-	25.11	-	1.79	2.34	0.85	12.17	3.49	53.40	18.82	97.50	25.56	257	57.50	8 675	0.78	443.5	309.5	48.41
21HK01-4-19	14.10	853.32	1 190	2.46	-	26.60	0.17	4.45	5.94	2.11	28.74	9.50	110.32	40.91	192.10	38.82	337	68.30	8 657	0.78	111.7	96.4	10.33
21HK01-4-20	17.36	877.66	1 233	2.36	-	48.28	-	4.36	7.10	1.77	34.98	10.31	112.03	42.17	198.96	35.08	316	63.68	9 729	0.92	123.6	141.6	11.52
21HK01-4-21	15.66	865.44	1 931	7.39	-	44.55	0.16	4.22	6.41	2.25	38.84	13.17	169.29	65.01	335.62	64.39	575	113.72	8 946	1.83	240.5	188.3	22.19
21HK01-4-22	17.66	879.76	922	2.29	-	26.18	0.23	3.55	4.73	2.00	21.63	7.45	84.79	31.05	154.68	29.91	258	52.14	9 035	0.69	84.6	81.2	8.63
21HK01-4-23	9.59	810.69	1 674	3.23	-	4.43	0.13	2.11	5.30	0.69	33.61	11.17	136.80	57.31	303.96	61.80	564	118.46	9 926	1.24	291.4	118.3	87.39
21HK01-4-24	-		1 419	3.17	-	4.14	0.16	2.11	2.73	0.28	26.72	8.86	117.48	51.20	274.82	55.95	514	107.78	9 976	1.36	260.7	101.3	68.81
21HK01-4-25	-		1 047	3.95	-	31.53	0.06	1.72	5.66	1.21	23.96	7.25	92.99	34.06	172.59	34.91	310	63.91	10 706	1.52	274.9	161.4	30.49
21HK01-4-26	-		1 142	4.20	-	40.33	-	2.48	5.48	1.05	27.17	7.71	97.51	36.79	188.63	35.75	341	69.14	10 250	1.39	246.5	164.7	30.19
21HK01-4-27	-		767	1.45	-	21.52	-	1.50	3.36	1.26	15.02	5.23	66.45	24.53	119.64	25.34	246	52.39	10 091	0.57	176.0	140.7	19.19
21HK01-4-28	13.29	846.51	1 824	2.65	0.61	28.86	0.62	8.20	8.81	3.20	36.77	12.19	142.59	58.69	287.18	65.47	623	129.09	8 202	0.78	246.6	293.7	22.39

Table 2

Fig.6

Table 3

Table 4

LA-ICP-MS trace element analysis results of the apatite grains from muscovite granite in Hukeng tungsten deposit（×10-6）"

测点编号	Na	Mg	Mn	Fe	Ga	As	Sr	Y	La	Ce	Pr	Nd	Sm	Eu	Gd	Tb	Dy	Ho	Er	Tm	Yb	Lu	Pb	Th	U
21HK01-4-01	1 290	8.4	8 596	203	15.3	0.08	89.98	3 186	322	1 189	217	1 139	1 087	33	1 412	219	958	101	192	19.3	94	10.3	12.5	7.5	1.08
21HK01-4-02	1 641	11.5	9 373	358	17.1	15.87	71.84	4 143	376	1 519	270	1 366	1 319	23	1 738	288	1 111	112	184	16.5	62	5.4	12.7	17.3	2.95
21HK01-4-05	971	8.3	6 191	90	4.6	5.40	84.44	2 094	196	843	162	947	815	20	1 029	139	510	51	81	6.9	30	2.8	10.9	2.4	0.32
21HK01-4-06	1 313	8.6	7 902	284	9.9	11.35	92.43	2 886	286	1 144	210	1 128	1 089	27	1 509	232	856	83	120	10.4	40	3.7	13.4	4.8	0.65
21HK01-4-07	1 304	6.8	8 568	244	10.3	15.94	68.18	3 108	278	1 168	220	1 159	1 146	23	1 473	214	860	85	132	10.4	44	4.2	11.9	5.9	0.85
21HK01-4-08	1 085	9.4	5 367	247	8.7	1.74	72.25	2 588	236	963	189	1 003	993	22	1 291	187	681	65	103	8.3	29	3.0	10.6	2.6	0.56
21HK01-4-10	521	9.6	6 401	184	3.8	4.31	108.82	1 509	58	350	88	574	802	15	1 091	174	558	47	57	4.5	15	0.9	15.7	-	-
21HK01-4-11	1 298	10.6	8 847	243	10.2	4.79	73.84	3 142	289	1 151	207	1 101	1 147	24	1 534	238	889	80	130	10.3	40	3.6	13.0	8.3	2.13
21HK01-4-13	1 916	14.9	9 180	223	15.5	7.63	58.80	4 501	360	1 413	262	1 395	1 864	22	2 637	422	1 415	111	157	13.6	47	3.2	12.6	18.2	5.72
21HK01-4-14	1 545	9.3	7 936	319	6.9	1.29	78.71	3 493	349	1 333	238	1 294	1 269	28	1 780	283	1 141	112	189	16.1	66	5.9	12.0	10.5	1.99
21HK01-4-15	1 524	8.2	8 653	370	9.1	9.74	73.97	3 634	298	1 207	238	1 260	1 346	23	1 761	275	1 015	95	153	13.4	48	4.9	10.9	4.2	0.71
21HK01-4-16	1 234	7.5	5 441	204	11.6	5.37	107.53	3 256	291	1 066	198	1 031	941	33	1 302	221	1 010	119	228	24.4	119	12.1	9.0	16.3	1.43
21HK01-4-17	1 397	8.2	9 963	332	8.7	12.36	90.45	3 338	307	1 163	227	1 220	1 227	27	1 592	220	843	81	134	10.6	42	4.0	14.3	4.4	1.00
21HK01-4-18	1 652	8.3	7 865	175	10.8	-	65.89	4 222	387	1 416	256	1 262	1 191	22	1 642	276	1 129	117	201	16.8	71	6.8	12.4	27.6	3.81
21HK01-4-20	1 459	7.3	8 312	203	14.0	1.53	70.57	3 514	354	1 348	242	1 277	1 175	23	1 568	244	947	96	158	13.1	57	5.8	12.2	15.6	2.18
21HK01-4-21	975	7.3	6 307	348	11.2	35.53	83.94	2 963	395	1 335	230	1 170	981	27	1 331	213	944	106	214	20.5	93	8.6	9.8	31.4	2.14
21HK01-4-22	1 464	24.1	13 948	1 011	16.0	11.95	71.54	3 394	311	1 292	260	1 286	1 549	23	2 043	301	969	82	122	9.7	40	3.5	16.6	4.5	0.64
21HK01-4-24	851	5.9	6 693	276	4.0	3.52	61.73	1 964	223	974	189	1 021	763	12	826	103	407	39	65	5.9	27	2.5	9.5	2.0	-
21HK01-4-25	1 606	12.6	12 550	655	13.8	8.04	98.06	4 246	356	1 387	256	1 309	1 498	27	2 048	313	1 221	114	188	15.7	57	5.0	19.4	5.6	0.49
21HK01-4-26	1 557	8.5	6386	165	12.1	19.37	80.66	3 756	325	1 349	244	1 304	1 306	25	1 744	274	1 133	114	203	18.6	74	7.5	11.3	47.4	3.79
21HK01-4-27	1 287	8.5	6 317	83	9.2	0.91	78.69	2 705	290	1 192	223	1 119	1 090	25	1 418	211	808	76	121	8.6	35	3.0	12.7	16.8	2.23
21HK01-4-28	1 600	8.8	6 966	176	12.2	9.91	78.52	3 512	379	1 384	250	1 245	1 231	35	1 677	286	1 240	135	243	20.7	95	8.6	12.2	36.8	3.35
21HK01-4-30	1 345	7.5	5 081	137	10.8	3.28	69.62	2 984	306	1 178	219	1 121	1 049	20	1 400	215	842	83	137	11.4	45	3.7	10.1	22.8	3.36
20HK01-4-31	2 127	9.0	7 925	275	17.2	10.50	71.93	5 081	563	2 036	344	1 624	1 575	27	2 078	354	1 492	162	295	29.3	130	12.5	11.3	45.0	5.59

Table 4

Fig.7

Fig.8

Fig.9

References 0

	Bea F， Pereira M D， Stroh A，1994.Mineral/leucosome trace-element partitioning in a peraluminous migmatite （a laser ablation-ICP-MS study）［J］.Chemical Geology，117（1/2/3/4）：291-312.
	Belousova E A， Griffin W L， O’Reilly S Y，et al，2002a.Apatite as an indicator mineral for mineral exploration：Trace-element compositions and their relationship to host rock type［J］.Journal of Geochemical Exploration，76（1）：45-69.
	Belousova E A， Griffin W L， O’Reilly S Y，et al，2002b.Igneous zircon：Trace element composition as an indicator of source rock type［J］.Contributions to Mineralogy and Petrology，143（5）：602-622.
	Belousova E A， Kostitsyn Y A， Griffin W L，et al，2010.The growth of the continental crust：Constraints from zircon Hf-isotope data［J］.Lithos，119（3/4）：457-466.
	Bureau of Geology and Mineral Exploration and Development of Jiangxi Province，1984.The Reginal Geology of Jiangxi，China［M］.Beijing：Geological Publishing House.
	Bureau of Geology and Mineral Exploration and Development of Jiangxi Province，2014.The Mineral Geological Records of China—Volume of Jiangxi Province［M］.Beijing：Geological Publishing House.
	Cao M， Li G， Qin K，et al，2012.Major and trace element characteristics of apatites in granitoids from Central Kazakhstan：Implications for petrogenesis and mineralization［J］.Resource Geology，62（1）：63-83.
	Chappell B W， White A J R，1992.I- and S-type granites in the Lachlan Fold Belt［J］.Earth and Environmental Science Transactions of the Royal Society of Edinburgh，83（1/2）：1-26.
	Chappell B W， White A J R，2001.Two contrasting granite ty-pes：25 years later［J］.Australian Journal of Earth Sciences，48（4）：489-499.
	Chen B， Ma X， Wang Z，2014.Origin of the fluorine-rich highly differentiated granites from the Qianlishan composite plutons （South China） and implications for polymetallic mineralization［J］.Journal of Asian Earth Sciences，93：301-314.
	Chen Maohong， Zhang Wei， Xiang Junfeng，et al，2009.Characteristics of the ore bearing ductile shear zones at Hukeng tungsten deposit and ⁴⁰Ar-³⁹Ar geochronological constraints［J］.Journal of Guilin University of Technology，29（2）：195-206.
	Chen X， Huang W， Chen L，et al，2021.Controlling factors of different Late Cretaceous granitoid-related mineralization between western margin of the Yangtze Block and the nei-ghbor Yidun arc［J］.Ore Geology Reviews，139：104554.
	Chen Yuchuan， Wang Denghong，2012.Four main topics concerning the metallogeny related to Mesozoic magmatism in South China［J］.Geotectonica et Metallogenia，36（3）：315-321.
	Doherty A L， Webster J D， Goldoff B A，et al，2014.Partitioning behavior ofchlorine and fluorine in felsic melte-fluid （s）-apatite systems at 50 MPa and 850-950 ℃［J］.Chemical Geology，384：94-111.
	Ferry J M， Watson E B，2007.New thermodynamic models and revised calibrations for the Ti-in-zircon and Zr-in-rutile thermometers［J］.Contributions to Mineralogy and Petrology，154（4）：429-437.
	Guo Lingzhi， Shi Yangshen， Ma Ruishi，1983.On the formation and evolution of the Mesozoic-Cenozoic active continental margin and island arc tectonics of the Western Pacific Ocean［J］.Acta Geologica Sinica，（1）：11-21.
	Guo Lingzhi， Shi Yangshen， Ma Ruishi，et al，1984.Tectonostratigraphic Terranes of Southeast China［J］.Journal of Nanjing University（Natural Science），（4）：732-739.
	Han Li， Huang Xiaolong， Li Jie，et al，2016.Oxygen fugacity variation recorded in apatite of the granite in the Dahutang tungsten deposit，Jiangxi Province，South China［J］.Acta Petrologica Sinica，32（3）：746-758.
	Hoskin P W O，2005.Trace-element composition of hydrothermal zircon and the alteration of Hadean zircon from the Jack Hills，Australia［J］.Geochimica et Cosmochimica Acta，69（3）：637-648.
	Hoskin P W O， Schaltegger U，2003.The composition of zircon and igneous and metamorphic petrogenesis［J］.Reviews in Mineralogy and Geochemistry，53（1）：27-62.
	Irber W，1999.The lanthanide tetrad effect and its correlation with K/Rb，Eu/Eu∗，Sr/Eu，Y/Ho，and Zr/Hf of evolving peraluminous granite suites［J］.Geochimica et Cosmochimica Acta，63（3/4）：489-508.
	Jia J， Du X， Zhao K，et al，2022.Sources of K-bentonites across the Ordovician-Silurian transition in South China：Implications for tectonic activities on the northern and southern margins of the South China Block［J］.Marine and Petroleum Geology，139：105599.
	Keppler H， Wyllie P J，1991.Partitioning of Cu，Sn，Mo，W，U，and Th between melt and aqueous fluid in the systems haplogranite-H₂O- HCl and haplogranite-H₂O- HF［J］.Contributions to Mineralogy and Petrology，109（2）：139-150.
	Laurent O， Zeh A， Gerdes A，et al，2017.How do granitoid magmas mix with each other？ Insights from textures，trace element and Sr-Nd isotopic composition of apatite and titanite from the Matok pluton（South Africa）［J］.Contributions to Mineralogy and Petrology，172（9）：1-22.
	Li H， Zhang H， Ling M X，et al，2011.Geochemical and zircon U-Pb study of the Huangmeijian A-type granite：Implications for geological evolution of the Lower Yangtze River belt［J］.International Geology Review，53（5/6）：499-525.
	Li J L， Schwarzenbach E M， John T，et al，2021a.Subduction zone sulfur mobilization and redistribution by intraslab fluid-rock interaction［J］.Geochimica et Cosmochimica Acta，297：40-64.
	Li J， Huang X L， Fu Q，et al，2021b.Tungsten mineralization during the evolution of a magmatic-hydrothermal system：Mineralogical evidence from the Xihuashan rare-metal granite in South China［J］.American Mineralogist：Journal of Earth and Planetary Materials，106（3）：443-460.
	Li W， Chakraborty S， Nagashima K，et al，2020.Multicomponent diffusion of F，Cl and OH in apatite with application to magma ascent rates［J］.Earth and Planetary Science Letters，550：116545.
	Li X， Yi X， Huang C，et al，2018.Zircon U-Pb，molybdenite Re-Os and muscovite Ar-Ar geochronology of the Yashan W-Mo and Xiatongling W-Mo-Be deposits：Insights for the duration and cooling history of magmatism and mineralization in the Wugongshan district，Jiangxi，South China［J］.Ore Geology Reviews，102：1-17.
	Liu J， Mao J， Ye H，et al，2011.Geology，geochemistry and age of the Hukeng tungsten deposit，southern China［J］.Ore Geology Reviews，43（1）：50-61.
	Liu Jun， Mao Jingwen， Ye Huishou，et al，2008a.Zircon LA-ICPMS U-Pb dating of Hukeng granit in Wugongshan area，Jiangxi Province and its geochemical characteristics［J］.Acta Petrologica Sinica，24（8）：1813-1822.
	Liu Jun， Xie Guiqing， Shi Guodong，et al，2010.Characteristics of ore-forming fluid of Hukeng tungsten deposit in Wugongshan area［J］.Mineral Deposit，29（Supp.1）：589-590.
	Liu Jun， Ye Huishou， Xie Guiqing，et al，2008b.Re-Os dating of molybdenite from the Hukeng tungsten deposit in the Wugongshan area，Jiangxi Province，and its geological implications［J］.Acta Geologica Sinica，（11）：1572-1579.
	Liu Y， Gao S， Hu Z，et al，2010.Continental and oceanic crust recycling-induced melt-peridotite interactions in the Trans-North China Orogen：U-Pb dating，Hf isotopes and trace elements in zircons from mantle xenoliths［J］.Journal of petrology，51（1/2）：537-571.
	Loader M A， Nathwani C L， Wilkinson J J，et al，2022.Controls on the magnitude of Ce anomalies in zircon［J］.Geochimica et Cosmochimica Acta，328：242-257.
	Loader M A， Wilkinson J J， Armstrong R N，2017.The effect of titanite crystallisation on Eu and Ce anomalies in zircon and its implications for the assessment of porphyry Cu deposit fertility［J］.Earth and Planetary Science Letters，472：107-119.
	Lou Fasheng， Shu Liangshu， Yu Jinhai，et al，2002.Petrological and geochemical characteristics and origin of the Wugongshan Dome Granit，Jiangxi Province［J］.Geological Review，（1）：80-88.
	Loucks R R， Fiorentini M L， Henríquez G J，2020.New magmatic oxybarometer using trace elements in zircon［J］.Journal of Petrology，61（3）：egaa034.
	Mao J， Liu P， Goldfarb R J，et al，2021.Cretaceous large-scale metal accumulation triggered by post-subductional large-scale extension，East Asia［J］.Ore Geology Reviews，136：104270.
	Mao J， Pirajno F， Cook N，2011.Mesozoic metallogeny in East China and corresponding geodynamic settings—An introduction to the special issue［J］.Ore Geology Reviews，43（1）：1-7.
	Mao J， Xiong B， Liu J，et al，2017.Molybdenite Re/Os dating，zircon U-Pb age and geochemistry of granitoids in the Yangchuling porphyry W-Mo deposit （Jiangnan tungsten ore belt），China：Implications for petrogenesis，mineralization and geodynamic setting［J］.Lithos，286：35-52.
	Mao Jingwen， Xie Guiqing， Guo Chunli，et al，2008.Spatial-temporal distribution of Mesozoic ore deposits in South China and their metallogenic settings［J］.Geological Journal of China Universities，14（4）：510-526.
	Mao M， Rukhlov A S， Rowins S M，et al，2016.Apatite trace element compositions：A robust new tool for mineral exploration［J］.Economic Geology，111（5）：1187-1222.
	Marks M A W， Scharrer M， Ladenburger S，et al，2016.Comment on“Apatite：A new redox proxy for silicic magmas？”［Geochimica et Cosmochimica Acta 132 （2014） 101-119］［J］.Geochimica et Cosmochimica Acta，183：267-270.
	Marks M A W， Wenzel T， Whitehouse M J，et al，2012.The volatile inventory （F，Cl，Br，S，C） of magmatic apatite：An integrated analytical approach［J］.Chemical Geology，291：241-255.
	Miles A J， Graham C M， Hawkesworth C J，et al，2014.Apatite：A new redox proxy for silicic magmas？［J］.Geochimica et Cosmochimica Acta，132：101-119.
	O’Sullivan G， Chew D， Kenny G，et al，2020.The trace element composition of apatite and its application to detrital provenance studies［J］.Earth-Science Reviews，201：103044.
	Pan Y， Fleet M E，2002.Compositions of the apatite-group minerals：Substitution mechanisms and controlling factors［J］.Reviews in Mineralogy and Geochemistry，48（1）：13-49.
	Piccoli P M， Candela P A，2002.Apatite in igneous systems［J］.Reviews in Mineralogy and Geochemistry，48（1）：255-292.
	Qu P， Li N B， Niu H C，et al，2019.Zircon and apatite as tools to monitor the evolution of fractionated I-type granites from the central Great Xing’an Range，NE China［J］.Lithos，348：105207.
	Qu P， Niu H C， Weng Q，et al，2022.Apatite and zircon geochemistry for discriminating ore-forming intrusions in the Luming giant porphyry Mo deposit，northeastern China［J］.Ore Geology Reviews，143：104771.
	Ren Jishun，1990.On the geotectonics of southern China［J］.Acta Geologica Sinica，（4）：275-288.
	Sadove G， Konecke B A， Fiege A，et al，2019.Structurally bound S^2-，S^1-，S⁴⁺，S⁶⁺ in terrestrial apatite：The redox evolution of hydrothermal fluids at the Phillips mine，New York，USA［J］.Ore Geology Reviews，107：1084-1096.
	Schaltegger U， Pettke T， Audétat A，et al，2005.Magmatic-to-hydrothermal crystallization in the W-Sn mineralized Mole Granite （NSW，Australia）：Part I：Crystallization of zircon and REE-phosphates over three million years—A geochemical and U-Pb geochronological study［J］.Chemical Geology，220（3/4）：215-235.
	Sha L K， Chappell B W，1999.Apatite chemical composition，determined by electron microprobe and laser-ablation inductively coupled plasma mass spectrometry，as a probe into granite petrogenesis［J］.Geochimica et Cosmochimica Acta，63（22）：3861-3881.
	Shi Yangshen， Shu Liangshu， Guo Lingzhi，et al，1995.On Plate Collision KIinematics：Taking the Jiangnan and the Eastern Tianshan Orogenic Belts as Examples［J］.Geological Journal of China Universities，（1）：11-21.
	Shu Liangshu，2012.An analysis of principal features of tectonic evolution in South China Block［J］.Geological Bulletin of China，31（7）：1035-1053.
	Shu Liangshu， Sun Yan， Wang Dezi，et al，1998.Mesozoic extensional structure of Wugongshan in South China［J］.Science in China（Series D：Earth Sciences），（5）：431-438.
	Song Z T， Xu X S，2022.Petrogenesis of high-maficity S-type granites：Insight from the early Paleozoic Jinxi granite，South China［J］.Lithos，412/413：106597.
	Stepanov A S， Hermann J， Rubatto D，et al，2012.Experimental study of monazite/melt partitioning with implications for the REE，Th and U geochemistry of crustal rocks［J］.Chemical Geology，300：200-220.
	Su S Q， Qin K Z， Li G M，et al，2021.Constraints on scheelite genesis at the Dabaoshan stratabound polymetallic deposit，South China［J］.American Mineralogist：Journal of Earth and Planetary Materials，106（9）：1503-1519.
	Sun J F， Yang J H， Zhang J H，et al，2021.Apatite geochemical and Sr-Nd isotopic insights into granitoid petrogenesis［J］.Chemical Geology，566：120104.
	Sun S S， McDonough W F，1989.Chemical and isotopic systematics of oceanic basalts：Implications for mantle composition and processes［J］.Geological Society，London，Special Publications，42（1）：313-345.
	Teiber H， Marks M A W， Wenzel T，et al，2014.The distribution of halogens （F，Cl，Br） in granitoid rocks［J］.Chemical Geology，374：92-109.
	Trail D， Watson E B， Tailby N D，2012.Ce and Eu anomalies in zircon as proxies for the oxidation state of magmas［J］.Geochimica et Cosmochimica Acta，97：70-87.
	Vermeesch P，2018.IsoplotR：A free and open toolbox for geochronology［J］.Geoscience Frontiers，9（5）：1479-1493.
	Virgo D， Mysen B O， Kushiro I，1980.Anionic constitution of 1-atmosphere silicate melts：Implications for the structure of igneous melts［J］.Science，208（4450）：1371-1373.
	Wang D， Shu L，2012.Late Mesozoic basin and range tectonics and related magmatism in southeast China［J］.Geoscience Frontiers，3（2）：109-124.
	Wang D， Wang X L， Cai Y，et al，2022.Exploring the Sn-W metallogenic potential of Late Jurassic Ganfang-Guyangzhai granite suite，South China：Zircon and apatite geochemistry［J］.Ore Geology Reviews，144：104863.
	Wang H Z， Chen P R， Sun L Q，et al，2015.Magma mixing and crust-mantle interaction in Southeast China during the Early Cretaceous：Evidence from the Furongshan granite porphyry and mafic microgranular enclaves［J］.Journal of Asi-an Earth Sciences，111：72-87.
	Wang T， Li G， Wang Q，et al，2019.Petrogenesis and metallogenic implications of Late Cretaceous I-and S-type granites in Dachang-Kunlunguan ore belt，southwestern South China Block［J］.Ore Geology Reviews，113：103079.
	Watson E B， Green T H，1981.Apatite/liquid partition coefficients for the rare earth elements and strontium［J］.Earth and Planetary Science Letters，56：405-421.
	Webster J D， Tappen C M， Mandeville C W，2009.Partitioning behavior of chlorine and fluorine in the system apatite-melt-fluid.II.Felsic silicate systems at 200 MPa［J］.Geochimica Cosmochimica Acta，73（3）：559-581.
	Wu Fujiang， Zhang Fangrong，2003.Features and genesis of Caledonian granites in the Wugongshan in the eastern segment of the northern maring of South China plate［J］.Geology in China，（2）：166-172.
	Xing C M， Wang C Y，2017.Cathodoluminescence images and trace element compositions of fluorapatite from the Hongge layered intrusion in SW China：A record of prolonged crystallization and overprinted fluid metasomatism［J］.American Mineralogist：Journal of Earth and Planetary Materials，102（7）：1390-1401.
	Xing K， Shu Q， Lentz D R，et al，2020.Zircon and apatite geochemical constraints on the formation of the Huojihe porphyry Mo deposit in the Lesser Xing’an Range，NE China［J］.American Mineralogist：Journal of Earth and Planetary Materials，105（3）：382-396.
	Xu W C， Luo B J， Xu Y J，et al，2018.Geochronology，geochemistry，and petrogenesis of late Permian to early Triassic mafic rocks from Darongshan，South China：Implications for ultrahigh-temperature metamorphism and S-type granite generation［J］.Lithos，308：168-180.
	Yan J， Liu X， Wang S，et al，2021.Metallogenic type controlled by magma source and tectonic regime：Geochemical comparisons of Mesozoic magmatism between the Middle-Lower Yangtze River Belt and the Dabie Orogen，eastern China［J］.Ore Geology Reviews，133：104095.
	Zhang Shaoli， Wang Liankui， Zhu Weifang，et al，1985.Use of REE in apatites to distinguish the petrogeno-minerlization series of granitic rocks［J］.Geochemica，（1）：45-57.
	Zhang Wei，2009.The Geological Features and Evolution of Metallogenic Tectonics of the Ore Bearing Quartz Veins at Hukeng Tungsten Deposit，Jiangxi Province［D］.Beijing：China University of Geosciences（Beijing）.
	Zhang Xiaobing，2020.Source，Magmatic Evolution and Hydrothermal Fluid Activity of Cretaceous Granites in the Coastal Region of SE China：Records from Apatite Geochemistry［D］.Guangzhou：Guangzhou Institute of Geochemistry，Chinese Academy of Sciences.
	Zhang Y， Ma D， Gao J F，2020.Origin and evolution of ore-forming fluids in a tungsten mineralization system，Middle Jiangnan orogenic belt，South China：Constraints from in-situ LA-ICP-MS analyses of scheelite［J］.Ore Geology Reviews，127：103806.
	Zhao W W， Zhou M F， Williams-Jones A E，et al，2018.Constraints on the uptake of REE by scheelite in the Baoshan tungsten skarn deposit，South China［J］.Chemical Geology，477：123-136.
	Zhou X， Sun T， Shen W，et al，2006.Petrogenesis of Mesozoic granitoids and volcanic rocks in South China：A response to tectonic evolution［J］.Episodes，29（1）：26.
	Zhou Xinmin，2003.My thinking about granite geneses of South China［J］.Geological Journal of China Universities，（4）：556-565.
	陈懋弘，章伟，向君峰，等，2009.江西浒坑钨矿含矿韧性剪切带及其⁴⁰Ar-³⁹Ar年代学约束［J］.桂林工学院学报，29（2）：195-206.
	陈毓川，王登红，2012.华南地区中生代岩浆成矿作用的四大问题［J］.大地构造与成矿学，36（3）：315-321.
	郭令智，施央申，马瑞士，1983.西太平洋中、新生代活动大陆边缘和岛弧构造的形成及演化［J］.地质学报，（1）：11-21.
	郭令智，施央申，马瑞士，等，1984.中国东南部地体构造的研究［J］.南京大学学报（自然科学版），（4）：732-739.
	韩丽，黄小龙，李洁，等，2016.江西大湖塘钨矿花岗岩的磷灰石特征及其氧逸度变化指示［J］.岩石学报，32（3）：746-758.
	江西省地质矿产勘查开发局，1984.江西省区域地质志［M］.北京：地质出版社.
	江西省地质矿产勘查开发局，2014.中国矿产地质志·江西卷［M］.北京：地质出版社.
	刘珺，毛景文，叶会寿，等，2008a.江西省武功山地区浒坑花岗岩的锆石U-Pb定年及元素地球化学特征［J］.岩石学报，24（8）：1813-1822.
	刘珺，谢桂青，施国栋，等，2010.武功山地区浒坑钨矿床成矿流体特征［J］.矿床地质，29（增1）：589-590.
	刘珺，叶会寿，谢桂青，等，2008b.江西省武功山地区浒坑钨矿床辉钼矿Re-Os年龄及其地质意义［J］.地质学报，（11）：1572-1579.
	楼法生，舒良树，于津海，等，2002.江西武功山穹隆花岗岩岩石地球化学特征与成因［J］.地质论评，（1）：80-88.
	毛景文，谢桂青，郭春丽，等，2008.华南地区中生代主要金属矿床时空分布规律和成矿环境［J］.高校地质学报，14（4）：510-526.
	任纪舜，1990.论中国南部的大地构造［J］.地质学报，（4）：275-288.
	施央申，舒良树，郭令智，等，1995.论板块碰撞运动学研究──以江南和东天山造山带为例［J］.高校地质学报，（1）：11-21.
	舒良树，2012.华南构造演化的基本特征［J］.地质通报，31（7）：1035-1053.
	舒良树，孙岩，王德滋，等，1998.华南武功山中生代伸展构造［J］.中国科学（D辑：地球科学），（5）：431-438.
	吴富江，张芳荣，2003.华南板块北缘东段武功山加里东期花岗岩特征及成因探讨［J］.中国地质，（2）：166-172.
	张绍立，王联魁，朱为方，等，1985.用磷灰石中稀土元素判别花岗岩成岩成矿系列［J］.地球化学，（1）：45-57.
	张晓兵，2020.中国东南沿海白垩纪花岗岩起源、演化和流体作用的磷灰石地球化学研究［D］.广州：中国科学院广州地球化学研究所.
	章伟，2009.江西浒坑钨矿含矿石英脉地质特征及其构造演化［D］.北京：中国地质大学（北京）.
	周新民，2003.对华南花岗岩研究的若干思考［J］.高校地质学报，（4）：556-565.

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测点编号	Th /（×10^-6）	U /（×10^-6）	Th/U	²⁰⁷Pb/²⁰⁶Pb		²⁰⁷Pb/²³⁵U		²⁰⁶Pb/²³⁸U		²⁰⁷Pb/²⁰⁶Pb		²⁰⁷Pb/²³⁵U		²⁰⁶Pb/²³⁸U
测点编号	Th /（×10^-6）	U /（×10^-6）	Th/U	比值	1s%	比值	1s%	比值	1s%	年龄/Ma	1s%	年龄/Ma	1s%	年龄/Ma	1s%
21HK01-4-1	265.5	281	0.94	0.055	22.787	0.168	20.660	0.024	4.002	777.7	5.725	145.2	0.557	150.2	0.119
21HK01-4-3	74.94	142	0.53	0.036	25.540	0.126	25.213	0.025	4.820	1631.4	3.730	107.2	0.532	158.0	0.150
21HK01-4-4	212.6	271	0.78	0.053	15.651	0.178	15.286	0.025	3.181	853.5	4.395	155.1	0.452	157.1	0.099
21HK01-4-7	236.2	334	0.71	0.048	19.815	0.166	20.635	0.025	3.505	564.0	7.182	143.5	0.563	157.0	0.109
21HK01-4-11	240.6	351	0.69	0.045	13.700	0.165	13.904	0.023	2.719	451.0	4.213	147.8	0.387	147.5	0.079
21HK01-4-15	476.3	644	0.74	0.072	13.732	0.234	13.667	0.024	3.158	596.5	6.397	205.9	0.514	153.0	0.096
21HK01-4-19	96.42	112	0.86	0.052	29.718	0.154	25.238	0.023	5.098	2494.1	6.116	124.1	0.605	149.5	0.151
21HK01-4-20	141.6	124	1.15	0.026	50.810	0.117	44.568	0.023	7.315	2210.9	7.666	93.8	0.851	147.2	0.213
21HK01-4-21	188.3	240	0.78	0.046	18.431	0.161	18.415	0.024	3.268	1013.6	4.640	139.1	0.485	150.9	0.098
21HK01-4-28	293.7	247	1.19	0.066	24.216	0.189	21.796	0.024	4.850	1237.9	6.560	158.5	0.641	151.7	0.145

测点编号	CaO	P₂O₅	TiO₂	K₂O	MnO	F	Cl	SO₃	SrO	FeO	ThO₂	Y₂O₃	Na₂O	MgO	Al₂O₃	Total
21HK01-4-01	54.21	41.08	-	0.004	1.00	3.54	0.004	0.028	0.004	0.01	0.027	0.28	0.20	-	0.040	98.94
21HK01-4-04	54.31	41.44	-	0.008	0.54	3.83	0.003	0.012	0.007	-	-	0.18	0.12	-	0.006	98.84
21HK01-4-05	52.94	41.50	-	0.003	1.43	3.84	0.012	0.026	-	0.03	0.005	0.30	0.25	-	-	98.72
21HK01-4-07	53.09	41.65	-	-	1.48	3.62	0.003	0.032	-	0.01	0.035	0.38	0.21	0.008	-	98.98
21HK01-4-08	53.81	41.79	0.00	-	1.28	3.56	0.001	0.028	0.012	0.03	0.021	0.36	0.20	-	0.010	99.61
21HK01-4-10	52.94	41.24	0.03	-	1.27	3.63	-	0.030	-	0.03	0.008	0.49	0.23	0.013	-	98.39
21HK01-4-11	54.99	42.70	-	-	0.75	3.62	-	-	-	0.03	-	0.22	0.04	0.004	0.001	100.84
21HK01-4-13	53.89	42.11	0.01	0.007	1.05	3.77	-	0.013	-	0.07	0.019	0.34	0.15	0.012	0.022	99.87
21HK01-4-14	54.21	41.27	0.03	-	0.77	3.65	-	0.013	-	0.03	-	0.28	0.16	-	0.073	98.94
21HK01-4-15	52.95	41.72	-	-	1.70	3.78	0.004	0.045	0.012	0.02	0.016	0.32	0.21	0.008	-	99.19
21HK01-4-17	52.53	42.22	0.01	-	2.34	3.52	0.003	-	0.001	0.03	-	0.52	0.21	-	-	99.90
21HK01-4-18	53.17	41.75	-	-	1.64	3.54	0.008	0.035	-	-	-	0.38	0.28	0.001	0.005	99.31
21HK01-4-19	54.31	43.22	0.02	-	0.67	4.09	0.003	0.023	0.001	0.01	0.018	0.26	0.17	-	0.007	101.06
21HK01-4-20	54.33	41.52	-	-	0.98	3.93	-	0.020	-	0.03	0.018	0.35	0.16	-	0.007	99.70

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[13]	ZHANG Yunqiang，CHEN Haiyan，LIU Yinglong，ZHANG Liguo，ZHANG Jianzhen，DONG Hongkai，LIU Guang，LIU Silin. LA-ICP-MS Zircon，U-Pb Age and Geochemical Characteristics of Quartz Monzonite of Shouwangfen Copper Mine in North Hebei Province [J]. Gold Science and Technology, 2014, 22(3): 23-29.
[14]	LV Ping，SUN Liangliang，LI Xuan，LIU Bo，HAO Shihe，SUN Yan，LI Shufang，CAO Zhenshuai. The Geochemical Characteristics and Prospecting Direction of Qinjiagou Poly-metallic Metallogensis，Inner Mongolia [J]. Gold Science and Technology, 2013, 21(3): 38-42.
[15]	LV Xiwang，SHI Wensheng，LIU Xinhui，GAO Jinggang. Geochemical Characteristics and Genesis Significance of Jinlongshan Stibonium-Gold Deposit，Shaanxi Province [J]. J4, 2012, 20(2): 1-7.

Trace Element Characteristics of Zircon and Apatite Metallogenic in Rocks of Hukeng Tungsten Deposit in Western Jiangxi Province：Implications for Petrogenesis and Mineralization

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