img

QQ群聊

img

官方微信

高级检索

黄金科学技术 ›› 2015, Vol. 23 ›› Issue (3): 99-104.doi: 10.11872/j.issn.1005-2518.2015.03.099

• 冶炼技术与装备研发 • 上一篇    

水滑石类材料在废水处理方面的应用进展

孙艳慧   

  1. 厦门紫金矿冶技术有限公司,福建  厦门   361101
  • 收稿日期:2015-01-15 修回日期:2015-04-02 出版日期:2015-06-28 发布日期:2015-11-16
  • 作者简介:孙艳慧(1981-),女,河南叶县人,工程师,从事冶金与矿山环保水处理研究工作。sunyanhui@zjky.cn

Application of Hydrotalcite-like Compounds in Water Treatment

SUN Yanhui   

  1. Xiamen Zijin Mining and Metallurgy Technology Co.,Ltd.,Xiamen   361101,Fujian,China
  • Received:2015-01-15 Revised:2015-04-02 Online:2015-06-28 Published:2015-11-16

摘要:

简要介绍了水滑石的结构、性质和水滑石类化合物的制备方法,并介绍了水滑石类化合物在印染废水、含磷酸根富营养废水、含卤素元素离子废水、含重金属离子废水及难降解有机物废水处理领域的应用情况。其中,含重金属离子废水处理方面的研究较深入系统,不仅有助于提高含重金属离子废水的资源化处理和回收水平,而且能够降低废水处理成本,在冶金、制革等行业具有较广阔的应用前景。最后,对水滑石类材料的应用现状及发展趋势进行了展望。

关键词: 水滑石类, 材料制备, 废水处理, 冶金

Abstract:

The structure,properties and preparation methods of hydrotalcite-like compounds were introduced firstly.Then,introduced the application of hydrotalcite compounds in the field of wastewater treatment,such as printing and dyeing wastewater,phosphates containing eutrophic wastewater,halogen containing wastewater and wastewater containing heavy metal ions and refractory organic wastewater.Of hydrotalcite compounds in the treatment of wastewater containing heavy metal ion research deeply,help to promote the improvement of resource disposal and recycling of metallurgical waste water and waste water treatment cost is reduced,has a broad application prospect.Finally,the application situation and prospects of hydrotalcite class materials is prospected.

Key words: hydrotalcite-like compounds, preparation, water treatment, Metallurgy

中图分类号: 

  • X703

[1]  燕丰.水滑石类层状化合物的生产及应用前景[J].乙醛醋酸化工,2008,(8):23-26.
[2] 景晓燕,郑崇辉,王慧颖,等.水滑石类化合物的研究现状及进展[J].应用科技,2004,31(10):41-42.
[3] 杨洪丽,李为民,郑晓林,等.水滑石制备及在酯交换反应中应用[J].常州大学学报:自然科学版,2007,19(2):19-22.
[4] 王立秋,王海增,李冬梅,等.水滑石对水溶性染料活性深蓝ST-2GLN脱色性能研究[J].矿物学报,2007,27(2):115-120.
[5] 王巧巧,倪哲明,张峰,等.镁铝二元水滑石的焙烧产物对染料废水酸性红88的吸附[J].无机化学学报,2009,25(12):2156-2162.
[6] 朱洪涛,马玉晶.镁铝铁三元类水滑石对印染废水的吸附性能研究[J].上海化工,2011,36(10):1-4.
[7] 朱国华,吴东辉.水滑石焙烧产物对弱酸艳红B吸附特性研究[J].化学研究与应用,2011,23(9):1200-1204.
[8] 严刚,张盛汉,成双,等.镁铝水滑石吸附氯离子性能研究[J].青海大学学报:自然科学版,2011,29(1):20-23.
[9] 赵正鹏,王海增,郭鲁钢,等.焙烧层状氢氧化镁铝对溴离子吸附性能研究[J].盐业与化工,2007,36(2):4-7.
[10] Liang L V,Jing He,Min Wei,et al.Factors infuencing the removal of fuoride from aqueous solution by calcined Mg-Al-CO3 layered double hydroxides[J].Journal of Hazardous Materials,2006,(133):119-128.
[11] 胡静,吕亮.镁铝水滑石去除氯离子性能研究[J].工业水处理,2008,28(6):59-61.
[12] 孔垂鹏,聂玉伦,胡春,等.Mg/Al/Fe复合氧化物吸附去除水体中氟化物的研究[J].环境工程学报,2010,1:110-114.
[13] 孔茜,杜倩.镁铝LDH制备表征及吸附磷酸根离子的性能研究[J].环境科学与技术,2011,34(3):102-105.
[14] 朱茂旭,李艳萍,张良,等.水滑石及其焙烧产物对磷酸根的吸附[J].矿物学报,2005,25(1):27-32.
[15] Koilraj P,Kannan S.Phosphate uptake behavior of ZnAlZr  ternary layered double hydroxides through surface precipitat[J].Journal of Colloid and Interface Science,2010,341:289-297.
[16] Akihiro S,Mark I J,James B M.Anionic surfactant enhanced phosphate desorption from Mg/Al-layered double hydroxides by micelle formation[J].Journal of Colloid and Interface Science,2013,411:1-7.
[17] 林宁,赵谨,秦立娟.磷酸根插层水滑石阻燃剂的研制[J].无机盐工业,2005,37(9):35-37.
[18] Calja G,Nakamura R,Niiyama H.Tailoringthe porous properties of iron containing mixed oxides for As(Ⅴ) removal from aqueous solutions[J].Microporous and Mesoporous Materials,2005,83(1-3):94-100.
[19] WangS L,HseuR J,ChangR R,et al.Adsorption and thermal desorption of Cr(VI) on Li/AI layered double hydroxide[J].Colloids and Surfaces A:Physicochem Eng Aspects,2006,277(1-3):8-14.
[20] Prasanna S V,Anantha Padmanabha Rao R, VishnuKamath P.Layered double hydroxides as potential chromate scavengers[J].Journal of Colloid and Interface Science,2006,304(2):292-299.
[21] 夏盛杰,倪哲明,潘国祥,等.Co/Mg/Al类水滑石对废水中Cr(VI)的吸附性能研究[J]. 浙江工业大学学报,2006,34(5):517-520.
[22] DasN N,KonarJ,Mohanta M K,et al.Adsorption of Cr(VI)and Se (Ⅳ) from their aqueous solutions onto Zr4+-substituted ZnAl/MgAl-layered double hydroxides:effect of Zr4+ substitution in the layer[J].Journal of Colloid and Interface Science,2004,270(1):1-8.
[23] Ferreira O P.Sandra Gomes de Moraes,Nelson Duran,et al.Evaluation of boron removal from water by hydrotalcite-like compounds[J].Chemosphere,2006,62 (1):80-88.
[24] Kameda J,Takeuchi H,Yoshioka T.Uptake of heavymetal ions from aqueous solution using Mg-Al layered double hydroxides intercalated with citrate,malate and tartrate[J].Separation and Purifeation Technology,2008,(62):330-336.
[25] Kameda T,Saito S,Umetsu Y.Mg-Al layered double hydroxide intercalated with ethylene  anion:Synthesis and application to the uptake of heavy metal ions from anaqueoussolution[J].Separation and Purification Teehnology,2005,(47):20-26.
[26] Perez M R,Pavlovic I,Barriga C,et al.Uptake of Cu2+,Cd2+ and Pb2+ on Zn-Al layered double hydroxide intercalated with edta[J].Applied Clay Science,2006,32(3-4):245-251.
[27] 林楠,沙宇.改性镁铝水滑石的合成及其对水中Cu2+的去除性能研究[J]. 水处理技术,2008,34(9):30-34.
[28] 李彦霖.超声辅助合成钙铝水滑石及其复合物对铬(Ⅵ)和铀(Ⅵ)的吸附[D].哈尔滨:哈尔滨工程大学,2013.
[29] 朱优峰,徐晓白,习志群.有机氯农药在多介质环境中迁移转化的研究进展[J].自然科学进展,2003,13(9):910-916.
[30] Guo Y,Li D,Hu C,et al.Photocatalytic degradation of aqueous Organocholorine pesticide on the layered double hydroxide pillared by paratungstate aion[J].Appl.Catal.B Environ,2001,30:337-349.
[31] 田志茗,高艳丽.水滑石类化合物—氧化铈催化剂的制备及其光降解甲基橙的性能研究[J].石油化工,2012,41(2):204-209.
[32] Cervilla A,Corma A,Fornes V,et al.Intercalation of[MoVIO2(O2CC(S)Ph2)2]2- in a Zn(Ⅱ)-Al (Ⅲ)layered double hydroxide host:A strategy for the heterogeneous catalysis of the air oxidation of thiols[J].Journal of the American Chemical Society,1994,116:1595-1596.
[33] Chibwe M,Pinnavaia T J.Stabilization of a cobalt(Ⅱ) phth-alocyanineoxidation catalyst by intercalation in a layered doublehydroxide host[J].Journal of the Chemical Society:Chemical Communications,1993,28(3):278-280.
[34] Hulea V,Maciuca A L,Fajula F,et al.Catalytic oxidation of thiophenes and thioethers with hydrogenperoxide in the presence of W-containing layered double hydroxides[J].Applied Catalysis A:General,2006,313(2):200-207.
[35] 王颖,曲久辉,刘会娟,等.Pd-Cu/水滑石吸附催化氢还原水中的硝酸根[J].科学通报,2006,51(7):786-791.

[1] 陈亚静,杨洪英*,佟琳琳,金哲男. 含砷矿石细菌氧化液除砷实验及砷钙渣稳定性研究[J]. 黄金科学技术, 2018, 26(1): 124-129.
[2] 宋永辉,姚迪,张珊,田宇红,兰新哲. 三维电极处理氰化废水的研究[J]. 黄金科学技术, 2017, 25(5): 116-121.
[3] 季常青. 水相中砷的形态分析及相关修复技术研究[J]. 黄金科学技术, 2016, 24(3): 111-115.
[4] 刘娅,吕翠翠,丁剑,钱鹏,李青春,叶树峰,陈运法. 氰化尾矿的絮凝实验研究[J]. 黄金科学技术, 2013, 21(6): 82-89.
[5] 李仕雄,李勇,徐忠敏,刘爱心. 焦亚硫酸钠破氰—电絮凝法处理黄金生产废水[J]. J4, 2012, 20(3): 66-69.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!