吸附法去除水中氰化物的研究进展

doi:10.11872/j.issn.1005-2518.2022.05.056

Abstract

Abstract:

Cyanide in cyanide-containing wastewater is a highly toxic substance.Leakage of cyanide-containing wastewater into the environment will cause environmental pollution of water and soil and damage human health.cyanide into the organism will release cyanide ion （CN^-），which will combine with the ferric iron oxidase in the mitochondria of cells，inhibit the reduction of ferric iron，hinder the normal respiration of cells，make cells lose the function of oxygen transfer，resulting in tissue hypoxia，leading to biological asphyxia and death. China has formulated strict standards for the discharge of cyanide wastewater.Therefore，it is necessary to carry out harmless treatment of cyanide-containing wastewater.Adsorption method is widely used in the treatment of cyanide-containing wastewater due to its advantages of simplicity，efficiency and economy.The widely used cyanide adsorption materials in the field of water treatment were reviewed，including carbonaceous adsorption materials，mineral materials，resin materials and new micro/nano materials，etc.The advantages and disadvantages of different adsorption materials in treating cyanide wastewater were compared.At the same time，the adsorption performance and mechanism of different adsorbents were discussed，mainly including the specific surface area of ??adsorbent materials，the treatment depth of cyanide，adsorption capacity，adsorption thermodynamics and kinetics.Adsorption mechanisms such as physical adsorption，chemical bonding，electrostatic attraction and ion exchange all occur in the adsorption of cyanide by adsorbent materials，such as activated carbon，zeolite，bentonite and other materials with rich pore structure for physical adsorption of cyanide.Metallic elements such as Cu，Zn，Fe and other metal elements in adsorbent materials can form metal complex cyanide chemical bond with CN^- in the solution.The anion in the ion exchange resin，quaternary ammonium salt or nitrate modified material can occur ion exchange with cyanide.The research directions of cyanide adsorption materials in the future are prospected to provide reference for the development and application of cyanide adsorption materials，such as further development of easy access，large adsorption capacity，small desorption coefficient，recyclable，easy to recover，green and environmental protection，no secondary pollution，high selectivity adsorption materials.

Key words: cyanide, adsorption material, adsorption mechanism, wastewater treatment, carbonaceous materials, micronanomaterials

CLC Number:

X703

Zuming NIE,Junhua TIAN,Zhongxian WU,Peiwei HAN,Jingmin YAN,Shufeng YE. Research Progress on Removal of Cyanide in Water by Adsorption[J].Gold Science and Technology, 2022, 30(5): 797-808.

Figures/Tables 2

Table 1

Adsorption capacity and mechanism of different materials for cyanide"

吸附材料	比表面积 /（m²·g^-1）	氰化物	氰化物浓度/（mg·L^-1）		最大吸附容量 /（mg·g^-1）	吸附等温模型	吸附动力学	吸附机理	文献来源
吸附材料	比表面积 /（m²·g^-1）	氰化物	处理前	处理后	最大吸附容量 /（mg·g^-1）	吸附等温模型	吸附动力学	吸附机理	文献来源
颗粒活性炭	506.3	Hg（CN）₂	1.0	0.19	0.14	Freundlich	拟二级动力学	物理吸附、化学吸附、离子交换	Aliprandini et al.，2020
Cu²⁺改性活性炭	-	CN^-	260	0.5	22.0	Langmuir	-	配体交换	张明祖等，2008
絮凝剂改性活性炭	-	CN^-	28.7	0.287	-	Langmuir	-	静电吸引	牟淑杰，2009
茶渣	-	CN^-	39.746	28.97	0.539	Langmuir	二级动力学	物理吸附	林业星等，2015
骨炭	116	CN^-	50	0.5	140	Langmuir	拟二级动力学	化学键作用	Asgari et al.，2012
金属有机树脂	1 651.9	Pt（CN）₄^2-；Co（CN）₆^3-；Cu（CN）₃^2-；Fe（CN）₆^3-	50	0.5	285；80；90；110	Langmuir	拟二级动力学	离子交换	Chen et al.，2019
MOR-2-QAS树脂	686	Pt（CN）₄^2-；Pd（CN）₄^2-	100~200	2	242.6；119.3	Langmuir	拟二级动力学	离子交换	Chen et al.，2021
D301树脂	-	Fe（CN）₆^3-	1 000	60	28.963	Freundlich	拟二级动力学	离子交换	宋永辉等，2008
膨润土	-	CN^-	472	9.44	-	-	-	物理吸附、化学键作用	许莹，2002
高岭土	-	CN^-	531	25	10.67	Freundlich	拟二级动力学	物理吸附、化学吸附	Behnamfard et al.，2019
煅烧蛋壳	-	CN^-	1 300	201.11	3.27	Langmuir	拟二级动力学	物理吸附	Eletta et al.，2016
LTA沸石	421	CN^-	25	0.125	31.25	Langmuir	拟二级动力学	物理吸附	Noroozi et al.，2018；Almusawi et al.，2018
Zr-MOFs	-	Pd（CN）₄^2-	102.4	1.8432	126	Langmuir	拟二级动力学	静电吸引、阴离子交换	叶群等，2020
Ni-Al 水滑石	142	CN^-	20	0.14	166	Langmuir	拟二级动力学	NO^3-与CN^-离子交换	Srinivasravuru et al.，2019
Mg-Al 水滑石	0.51	CN^-	372	37.2	60	Langmuir	拟二级动力学	物理化学	Alaei et al.，2020
纳米零价铁	-	CN^-	50	0.51	277.77	Langmuir	拟二级动力学	化学键作用	Tyagi et al.，2018
石墨烯	-	CN^-	260	5.2	483.74	Langmuir	拟二级动力学	物理吸附	Shadman et al.，2021
过氧化锌	-	CN^-	0.5	0.0035	2.205	Langmuir，Freundlich	拟二级动力学	静电吸引、化学键作用	Uppal et al.，2017
MOFs	210.6	Pd（CN）₄^2-；Co（CN）₆^3-；Fe（CN）₆^3-	50.1	0.45	172.9；101.0；102.6	Langmuir	拟二级动力学	离子交换、静电吸引、范德华力	Zhang et al.，2018

Table 1

Table 2

References 0

	Alaei R， Javanshir S， Behnamfard A，2020.Treatment of gold ore cyanidation wastewater by adsorption onto a hydrotalcite-type anionic clay as a novel adsorbent［J］.Journal of Environmental Health Science and Engineering，18：779-791.
	Aliprandini P， Veiga M M， Marshall B G，et al，2020.Investigation of mercury cyanide adsorption from synthetic wastewater aqueous solution on granular activated carbon［J］.Journal of Water Process Engineering，34：101154.
	Aliprandini P， Veiga M M， Marshall B G，et al，2020.Investigation of mercury cyanide adsorption from synthetic waste water aqueous solution on granular activated carbon［J］.Journal of Water Process Engineering，34：101154.
	Almusawi T J， Brouers F， Zarrabi M，et al，2018.What can the use of well-defined statistical functions of pollutants sorption kinetics teach us？ A case study of cyanide sorption onto LTA zeolite nanoparticles［J］.Environmental Technology and Innovation，10：46-54.
	Asgari G， Ramavandi B， Mohammadi A，et al，2012.The investigation of kinetic and isotherm of cyanide adsorption onto bone charcoal［J］.International Proceedings of Chemical Biological and Environmenta，43（25）：119-124.
	Barola C E C， Dusaban I F C， Olegario S E M，et al，2019.The effect on the zeta potential of surface modified Philippine natural zeolites（SM-PNZ） for the adsorption of anionic solutions［J］.Materials Science and Engineering，478：012039.
	Behnamfard A， Chegni K， Alaei R，et al，2019.The effect of thermal and acid treatment of kaolin on its ability for cyanide removal from aqueous solutions［J］.Environmental Earth Sciences，78：408.
	Chen M H， Li S L， Jin C，et al，2021.Removal of metal-cyanide complexes and recovery of Pt（Ⅱ） and Pd（Ⅱ） from waste water using an alkali-tolerant metal-organic resin［J］.Journal of Hazardous Materials，406：124315.
	Chen M H， Ye Q， Jiang S S，et al，2019.Two-step elution recovery of cyanide platinum using functional metal organic resin［J］.Molecules，24：2779.
	Chen Zhen， Sun Xiaogang， Yang Qi，et al，2019.Multiplicated modification of sepiolite and its removal performance of cyanide from coking wastewater［J］.Journal of Hunan Institute of Engineering，29（4）：72-77.
	Deveci H， Yazici E Y， Alp I，et al，2006.Removal of cyanide from aqueous solutions by plain and metal-impregnated granular activated carbons［J］.International Journal of Mi-neral Processing，79（3）：198-208.
	Dong Kaiwei， Bai Yunlong， Xie Feng，et al，2020.Review on recovery technologies of cyanide-containing wastewater［J］.Nonferrous Metals（Extractive Metallurgy），（4）：75-83.
	El-Aila H J， Elsousy K M， Hartany K A，2016.Kinetics，equilibrium，and isotherm of the adsorption of cyanide by MDFSD［J］.Arabian Journal of Chemistry，9：S198-S203.
	Eletta O A A， Ajayi O A， Ogunleye O O，et al，2016.Adsorption of cyanide from aqueous solution using calcinated eggshells：Equilibrium and optimisation studies［J］.Journal of Environmental Chemical Engineering，4：1367-1375.
	Gong Chunlong， Du Shufen， Zhang Wei，2007.Experimental investigation on cyanide wastewater treatment with ion-exchange resins［J］.Gold，28（2）：51-52.
	Gupta N， Balomajumder C， Agarwal V K，2012.Adsorption of cyanide ion on pressmud surface：A modeling approach［J］.Chemical Engineering Journal，191：548-556.
	Hang Shuguang， Yang Xiaoxu， Wang Fuli，et al，2007.Modification of bentonite and its application in wastewater treatment［J］.China Non-metallic Minerals Industry，（4）：21-23.
	He Min， Zhu Guocai， Lan Xinzhe，2010.Study on the adsorption properties and principles of D261 macroporous resin for cyanide［J］.Gold，31（9）：52-55.
	Hu Yangjia， He Zheng， Zhao Zhiqiang，et al，2015.The research progress of cyanidation-leaching wastewater treatment［J］.China Mining Magazine，24（Supp.1）：219-223.
	Huang Tianhao， Lin Lei， Wang Chenyi，et al，2019.Research and application of nitrogen and phosphorus removal material［J］.New Chemical Materials，47（3）：39-46.
	Jia Yuansheng， Zhang Wenbin，1988.Adsorption of low concentration cyanide by granular activated carbon［J］.Heilongjiang Environmental Journal，22（2）：62-65.
	Li Gugong，2020.Study on the Removal of Typical Pollutants in Water by Chitosan Stabilized Nano-silver Modified Tea Residue Biochar［D］.Guangzhou：South China University of Technology.
	Li Xueping， Zhong Hong， Zhou Li，2012.Research progress of cyanide-containing wastewater treatment［J］.Energy Che-mical Industry，33（2）：17-23.
	Liang Ying，2014.Purification of Electroplating Wastewater Containing Cyanide and Heavy Metal by In-situ Synthetic of Layered Double Hydroxides and Double Metal Complexes［D］.Shanghai：Shanghai University.
	Liao Zan， Lan Xinzhe， Zhu Guocai，2008.Adsorption property and mechanism of 201×7 strongly basic anion exchange resin for cyanide［J］.Gold，29（7）：46-50.
	Lin Yexing， Wang Zibo，2015.Adsorption characteristic of modified tea dregs for cyanide in electroplating wastewater［J］.Environmental Engineering，33（Supp.1）：120-122.
	Liu Huaqiu， Fu Rongbing， Wen Dongdong，et al，2020.Study on adsorption and removal efficiency of granular activated carbon for cyanide in groundwater contaminated by tailings［J］.Environmental Chemistry，39（12）：3531-3541.
	Liu Y L， Cheng H， He Y T，2020.Application and mechanism of sludge-based activated carbon for phenol and cyanide removal from bio-treated effluent of coking wastewater［J］.Process，8（1）：82.
	Liu Yali， Li Xin， Jing Zhaoqian，et al，2019.Application of low-temperature aqueous ammonia-modified sludge-based activated carbon to coking wastewater treatment［J］.Industrial Water Treatment，39（1）：25-28.
	Ma Pingjie，2017.Research progress in cyanide treatment of gold mine tailings and wastewater［J］.China New Technologies and Products，（6）：109-110.
	Maulana I， Takahashi F，2018.Cyanide removal study by raw and iron-modified synthetic zeolites in batch adsorption experiments［J］.Journal of Water Process Engineering，22：80-86.
	Miao Chen， Mou Shujie，2010.Study on adsorption treatment of wastewater containing cyanide with modified with rectorite［J］.Science Technology and Engineering，10（16）：4096-4099.
	Miao Tengfei， Bai Yang， Shi Bin，2020.Study on the treatment of cyanide containing wastewater［J］.World Nonferrous Metals，（4）：279-281.
	Mondal M， Mukherjee M， Sinha A，et al，2019.Removal of cyanide from steel plant effluent using coke breeze，a waste product of steel industry［J］.Journal of Water Process Engineering，28：135-143.
	Mou Shujie，2009.Experimental study on adsorption treatment of wastewater containing cyanide with modified PAC［J］.Gold，30（3）：56-58.
	Noroozi R， Almusawi T J， Kazemian H，et al，2018.Removal of cyanide using surface-modified Linde Type-A zeolite nanoparticles as an efficient and eco-friendly material［J］.Journal of Water Process Engineering，21：44-51.
	Oulego P， Collado S， Laca A，et al，2014.Simultaneous oxidation of cyanide and thiocyanate at high pressure and temperature［J］.Journal of Hazardous Materials，280：570-578.
	Rice N C， Rauscher R A， Wilkins W L，et al，2019.Behavioural and physiological assessments of dimethyl trisulfide treatment for acute oral sodium cyanide poisoning［J］.Basic & Clinical Pharmacology & Toxicology，125（3）：289-303.
	Shadman S， Massinaei M， Moghaddam A Z，2021.Removal of cyanide from the gold cyanidation plant tailings using graphene‑based magnetic nanocomposites［J］.Chemical Papers，75（10）：5543-5560.
	Shi Tongji，2001.Discussion on developing technique status extracting gold from cyanide［J］.Gold Science and Technology，9（6）：22-29.
	Song Yonghui， Lan Xinzhe， Li Xiuling，2008.Adsorption behavior and mechanism of D301 resin for Fe（Ⅲ） and CN^- in iron-cyanide solution［J］.Chinese Journal of Nonferrous Metals，18（1）：S160-S165.
	Srinivasravuru S， Jana A， De S，2019.Synthesis of NiAl-layered double hydroxide with nitrate intercalation：Application in cyanide removal from steel industry effluent［J］.Journal of Hazardous Materials，373：791-800.
	Su T， Song Y H， Lan X Z，et al，2019.Adsorption optimized of the coal-based material and application for cyanide wastewater treatment［J］.Green Processing and Synthesis，8（1）：391-398.
	Sun Huifang， He Binbin， Guo Dongsheng，2009.Modified coke deal with coke waste water by adsorption［J］.Technology of Water Treatment，35（10）：55-58.
	Sun Peijie， Wang Linping， Xu Lejin，2021.Advances in the treatment of cyanide in coking wastewater［J］.Chemical Industry and Engineering Progress，40（Supp.1）：386-396.
	Tan Shaodong， Luo Ling， Peng Guangwen，et al，2014.Advanced treatment of coking wastewater by resin absorption method［J］.Fuel & Chemical Processes，45（6）：53-55.
	Tyagi M， Rana A， Kumari S，et al，2018.Adsorptive removal of cyanide from coke oven wastewater onto zero-valent iron：Optimization through response surface methodology，isotherm and kinetic studies［J］.Journal of Cleaner Production，178：398-407.
	Uppal H， Tripathy S， Chawla S，et al，2017.Study of cyanide removal from contaminated water using zinc peroxide nanomaterial［J］.Journal of Environmental Sciences，55：76-85.
	Wang Li， Zhu Xixi，2013.Review on preparation and adsorption of mineral-based porous material［J］.Materials Reports，27（3）：48-52.
	Wang Ling， Yang Sanming， Wu Biao，2010.Experimental study on treatment of cyanide wastewater with copper-loaded activated carbon［J］.Environmental Impact Assessment，3（1）：13-16.
	Wang Qi， Zhu Zhengzhen， Li Yaoming，1985.Study on pore structure of carbonaceous materials［J］.Petrochemical Technology，14（6）：342-345.
	Wang Xiaomin， Kang Li，2016.Research progress on advanced treatment for coking wastewater［J］.Tianjin Chemical Industry，30（1）：6-9.
	Xiong Q， Jiang S J， Fang R，et al，2021.An environmental-friendly approach to remove cyanide in gold smelting pulp by chlorination aided and corncob biochar：Performance and mechanisms［J］.Journal of Hazardous Materials，408：124465.
	Xu Ying，2002.The experimental study of new types of water purification agents for cyanide-containing waste water［J］.Journal of North China University of Science and Technology，24（3）：67-71.
	Yan Chunhua，2021.Progress of cyanide-containing wastewater treatment technology［J］.Chemical and Pharmaceutical En-gineering，42（4）：65-71.
	Ye Qun， Chen Muhan， Xie Xiaoguang，et al，2020.Adsorption and separation of Pd（CN）₄ ^2- using pyridine quaternary-ammonium-functionalized Zr-MOFs［J］.Journal of Yunnan University（Natural Sciences Edition），42（4）：726-732.
	Ye Qun，2020.Preparation of Three Quaternary Ammonium Group Modified Adsorbents and Study on Their Performance of Palladium Cyanide Separation［D］.Yunnan：Yunnan University.
	You Dandan，2017.Application of activated carbon in the industrial wastewater［J］.West Leather，（1）：42-43.
	Yu Han， Hu Xianzhi，2010.Review of gold-leaching technologies by cyanidation and non-cyanidation［J］.Yunnan Metallurgy，39（3）：9-12.
	Yu Hong， Xie Lie， Cai Xiang，et al，2019.Research progress of recovery of gold complex by activated carbon from leaching liquid［J］.Multipurpose Utilization of Mineral Resources，（1）：28-33.
	Zhang Mingzu， Liu Jian，2008.Study on modification of activated carbon by ion and CN^- elimination in waste water［J］.Gold，29（6）：51-54.
	Zhang Q， Chen M H， Zhong L J，et al，2018.Highly effective removal of metal cyanide complexes and recovery of palladium using quaternary-ammonium-functionalized MOFs［J］.Molecules，23：2086.
	Zhang Quanxing， Li Aimin， Pan Bingcai，2015.The development of ion exchange and adsorption resin and its application in industrial wastewater treatment and resource reuse［J］.Polymer Bulletin，9：21-43.
	Zhang Wei，2018.Progress in the application of bentonite to the adsorption for inorganic pollutants in water pollution control［J］.Industrial Water Treatment，38（11）：10-16.
	Zhao Qingsong， Wang Yanqi， Dai Yan，et al，2013.Utilization of new micro/nano materials as potential adsorbents for removal of dye pollutants［J］.Journal of Tiangong University，32（5）：33-37.
	Zhou Jun， Wang Lijun， Zhang Hua，et al，2015.Study on adsorption of gold cyaniding leaching wastewater by A-21S resin and 201×7 resin［J］.Nonferrous Metals（Extractive Metallurgy），（11）：55-59.
	Zhou Jun， Zhang Hua， Song Yonghui，et al，2015b.Problems and solutions of treatingiron-bearing cyanide gold leaching solution by ion exchange method［J］.Nonferrous Metals（Extractive Metallurgy），（10）：71-74.
	陈镇，孙小刚，阳祺，等，2019.海泡石的复合改性及对焦化废水中氰化物的去除性能研究［J］.湖南工程学院学报，29（4）：72-77.
	董凯伟，白云龙，谢锋，等，2020.氰化废水回收技术综述［J］.有色金属（冶炼部分），（4）：75-83.
	巩春龙，杜淑芬，张微，2007.离子交换树脂处理含氰废水的试验研究［J］.黄金，28（2）：51-52.
	杭曙光，杨肖旭，王福利，等，2007.膨润土的改性及其在废水处理中的应用［J］.中国非金属矿工业导刊，（4）：21-23.
	何敏，朱国才，兰新哲，2010.D261大孔树脂吸附氰化物的性能及机理研究［J］.黄金，31（9）：52-55.
	胡杨甲，贺政，赵志强，等，2015.氰化浸出废水处理方法研究进展［J］.中国矿业，24（增1）：219-223.
	黄添浩，林磊，王趁义，等，2019.吸氮除磷材料的研究和应用现状［J］.化工新型材料，47（3）：39-46.
	贾生元，张文斌，1988.颗粒状活性炭对低浓度氰化物的吸附［J］.黑龙江环境通报，22（2）：62-65.
	李故功，2020.壳聚糖稳定纳米银改性茶叶渣生物碳去除水中典型污染物研究［D］.广州：华南理工大学.
	李雪萍，钟宏，周立，2012.含氰废水处理技术研究进展［J］.能源化工，33（2）：17-23.
	梁颖，2014.层状双金属氢氧化物及双金属氰化物原位形成调控对含氰重金属电镀废水的净化效果及其机理［D］.上海：上海大学.
	廖赞，兰新哲，朱国才，2008.201×7强碱性阴离子交换树脂对氰化物的吸附性能及吸附机理［J］.黄金，29（7）：46-50.
	林业星，王子波，2015.改性茶渣对电镀废水中氰化物的吸附特性［J］.环境工程，33（增1）：120-122.
	刘华秋，付融冰，温东东，等，2020.颗粒活性炭对尾渣污染地下水中氰化物的吸附去除效能［J］.环境化学，39（12）：3531-3541.
	刘亚利，李欣，荆肇乾，等，2019.低温氨水改性污泥活性炭处理焦化废水的应用［J］.工业水处理，39（1）：25-28.
	马平杰，2017.金矿尾矿及废水中氰化物的处理研究进展［J］.中国新技术新产品，（6）：109-110.
	苗晨，牟淑杰，2010.改性累托石吸附处理含氰废水实验研究［J］.科学技术与工程，10（16）：4096-4099.
	苗腾飞，白杨，师彬，2020.含氰废水处理方法研究［J］.世界有色金属，（4）：279-281.
	牟淑杰，2009.改性活性炭处理含氰废水的试验研究［J］.黄金，30（3）：56-58.
	石同吉，2001.氰化提金技术发展现状评述［J］.黄金科学技术，9（6）：22-29.
	宋永辉，兰新哲，李秀玲，2008.D301树脂对铁氰溶液中Fe（Ⅲ）及CN^-的吸附行为及机理［J］.中国有色金属学报，18（1）：S160-S165.
	孙慧芳，和彬彬，郭栋生，2009.焦炭及其改性吸附预处理焦化废水的试验研究［J］.水处理技术，35（10）：55-58.
	孙培杰，王林平，徐乐瑾，2021.焦化废水中氰化物的处理技术研究进展［J］.化工进展，40（增1）：386-396.
	谭绍栋，罗玲，彭光文，等，2014.树脂吸附法对焦化废水的深度处理［J］.燃料与化工，45（6）：53-55.
	汪玲，杨三明，吴飚，2010.载铜活性炭处理含氰废水的试验研究［J］.三峡环境与生态，3（1）：13-16.
	王力，主曦曦，2013.矿物基多孔材料的制备及其吸附研究进展［J］.材料导报，27（3）：48-52.
	王琪，朱铮真，李耀明，1985.炭质材料的孔结构研究［J］.石油化工，14（6）：342-345.
	王潇敏，康丽，2016.焦化废水深度处理技术的研究进展［J］.天津化工，30（1）：6-9.
	许莹，2002.几种新型含氰废水净化剂的研制［J］.河北理工学院学报，24（3）：67-71.
	晏春华，2021.含氰废水处理技术进展［J］.化工与医药工程，42（4）：65-71.
	叶群，2020.三种季铵基团修饰吸附剂的制备及其分离氰化钯性能研究［D］.云南：云南大学.
	叶群，陈慕涵，谢小光，等，2020.吡啶季铵Zr-MOFs吸附分离Pd（CN）₄ ^2- ［J］.云南大学学报（自然科学版），42（4）：726-732.
	游丹丹，2017.活性炭在工业废水中的应用［J］.西部皮革，（1）：42-43.
	余洪，谢蕾，蔡祥，等，2019.活性炭吸附回收浸出液中金络合物的研究进展［J］.矿产综合利用，（1）：28-33.
	玉涵，胡显智，2010.氰化及非氰化提金方法综述［J］.云南冶金，39（3）：9-12.
	张明祖，刘建，2008.活性炭负载离子改性及其去除水中氰离子的研究［J］.黄金，29（6）：51-54.
	张全兴，李爱民，潘丙才，2015.离子交换与吸附树脂的发展及在工业废水处理与资源化中的应用［J］.高分子通报，9：21-43.
	张巍，2018.膨润土在水污染治理中吸附无机污染物的应用进展［J］.工业水处理，38（11）：10-16.
	赵庆松，王艳旗，代彦，等，2013.新型微/纳米材料在染料污染吸附去除上的应用［J］.天津工业大学学报，32（5）：33-37.
	周军，王丽军，张华，等，2015a.A-21S和201×7树脂吸附处理氰化提金废水研究［J］.有色金属（冶炼部分），（11）：55-59.
	周军，张华，宋永辉，等，2015b.离子交换法处理含铁氰化提金尾液问题及解决办法［J］.有色金属（冶炼部分），（10）：71-74.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed

Comments

Recommended 10

[1]	JIANG Qi, WANG Rong-Chao. [J]. J4, 2010, 18(4): 37 -40 .
[2]	BAI Bi-Xin, WANG Shan-Gong, AN Zhi-Hai. Research and Application of Underground Mining Exploiting 3D Visualization System in Xinhui Gold Mine[J]. J4, 2011, 19(1): 55 -57 .
[3]	QU Hui, SHI Rui-Min. Analysis On Structure Conditions of Dongan Gold Deposit in HeilongjiangProvine[J]. J4, 2007, 15(1): 23 -25 .
[4]	SONG He-Min, FENG Chi-Li, DING Xian-Hua. Geological-Geochemical Charicteristics and Prospecting Direction of Jiaojiekou Mining Area, North Part of Taihang Mountain[J]. J4, 2010, 18(3): 54 -58 .
[5]	HU Qin-Xia, SUN Ban, GANG Yu, LI Chu-Fang, ZHANG Ku-Xiao. Geological Features and Genesis of Beijinshan Gold Deposit，Gansu Province[J]. J4, 2010, 18(6): 18 -21 .
[6]	LIN Hai-Ping. The Tectonic Evolution of Shear Zone and Gold Mineralization of Hetai Gold Mine[J]. J4, 2010, 18(6): 30 -33 .
[7]	YAN Wenqiang，YANG Fengxi. Discussion on Wudaoling Molybdenum Deposit"s Geological Mineralization Roles by Yicuomao Rock[J]. J4, 2008, 16(3): 37 -39 .
[8]	YAN Wengqiang, GAO Shuoxue, YANG Fengxi , TENG Yun. controlling factors and prospeting direction of wudaogou gold deposit[J]. J4, 2008, 16(3): 43 -44 .
[9]	CHEN Li-Zi, CAO Dong-Hong, YANG De-Mei. Element Geochemical Characteristics of Guloushan Ore Section in Jinlongshan Gold Mine,Shaanxi Province[J]. J4, 2011, 19(1): 28 -33 .
[10]	WANG Yanxue. Metallogenic Condition and Prospecting Orientation of Eerqisi Gold Zone，Xinjiang provinc[J]. J4, 2008, 16(3): 17 -20 .

吸附材料	优点	缺点	材料成本 /（元·t^-1）	来源文献
活性炭	比表面积大、孔隙结构发达、化学稳定性高	吸附率低、热稳定性差	约45.45	Gupta et al.，2012；Aliprandini et al.，2020
生物质炭	性能优良、原料充足、成本低廉	制作过程易产生二次污染	约4.29	林业星等，2015；Asgari et al.，2012；Liu et al.，2020；Mondal et al.，2019；孙慧芳等，2009；李故功，2020
树脂	吸附性能好、吸附容量大、适应氰化物浓度范围广	选择性差、铁氰化物解吸困难	约43.33	谭绍栋等，2014；周军等，2015b
黏土矿物材料	原料充足、价格低廉、制备简单	有效成分少、吸附容量小	约7.2	王力等，2013；张巍，2018；杭曙光等，2007
沸石	比表面积大、孔隙结构均一、吸附性能好	吸附速率慢	约6.4	Noroozi et al.，2018；Maulana et al.，2018
石墨烯	导电性好、比表面积大、机械强度高、重复利用率高	容易堆积结块，制作方法复杂	约1 447	Shadman et al.，2021
金属有机骨架（MOFs）	吸附位点分布均匀、活性点位多、吸附性能好	稳定性低、难以分离	约3 968	Zhang et al.，2018；叶群，2020
水滑石（LDH）	孔隙可调变、吸附容量大	制备过程繁琐	约700	Srinivasravuru et al.，2019；Alaei et al.，2020；梁颖，2014

[1]	Bo YANG,Xiong TONG,Xian XIE,Xiao WANG. Study on the Gold Recovery from Flotation Tailings of a Refractory Gold Ores in Gansu Province by a Process Combining Mineral Processing and Metallurgy [J]. Gold Science and Technology, 2020, 28(2): 285-292.
[2]	Li XIAO,Yongliang WANG,Peng QIAN,Jian DING,Shufeng YE. Advances in Non-cyanide Process for Gold Smelting [J]. Gold Science and Technology, 2019, 27(2): 292-301.
[3]	Wenqiang ZHAO,Chuanjin JIANG,Baobao SHI. Optimization Study on the Sulfur Separation Process for Cyanide Tailing [J]. Gold Science and Technology, 2019, 27(1): 129-136.
[4]	Shaoyuan SHI,Junqiang WANG,Yongchun WANG,Guodong WANG,Manman ZHANG,Zhi SUN. Research and Practice of Deep Purification and Desalination Reuse Technology for Complex Gold Wastewater [J]. Gold Science and Technology, 2018, 26(4): 535-542.
[5]	ZHAO Hefei，YANG Hongying，ZHANG Qin，TONG Linlin，JIN Zhenan，CHEN Guobao. Research Status of Factors Influence on Leaching of Gold with Thiosulfate [J]. Gold Science and Technology, 2018, 26(1): 105-114.
[6]	SONG Xuewen，ZHU Jiaqian，LUO Zengxin，CHEN Bo. Study on the Gold Flotation Technology and Process Mineralogy of a Cyanide Residue [J]. Gold Science and Technology, 2018, 26(1): 89-97.
[7]	DANG Xiao’e，WANG Lu，MENG Yusong，SONG Yonghui，Lü Chaofei. Performance of an Environmental Gold Leaching Agent and Activated Carbon Adsorption Characteristics of Gold in the Liquid [J]. Gold Science and Technology, 2017, 25(6): 114-120.
[8]	QIU Xuemin，CHEN Guobao，ZHANG Qin，YANG Hongying. Experimental Study on Flotation Recovery of Valuable Metals from Ultrafine Cyanide Tailing Containing High Grade Lead and Zinc [J]. Gold Science and Technology, 2017, 25(6): 61-67.
[9]	TU Yubo，HAN Peiwei，FU Guoyan，WEI Lianqi，ZHANG Xiaomeng，YU Bo，YE Shufeng. Study on the Curing Properties of Different Cementitious Materials for Cyanide Waste Residue [J]. Gold Science and Technology, 2017, 25(5): 135-139.
[10]	SONG Yonghui，YAO Di，ZHANG Shan，TIAN Yuhong，LAN Xinzhe. Study on the Treatment of Cyanide Wastewater by Three-dimensional Electrode [J]. Gold Science and Technology, 2017, 25(5): 116-121.
[11]	DANG Xiao’e，MENG Yusong，WANG Lu，SONG Yonghui，LV Chaofei，YUN Yaxin. Application Status and Development Trend of Two New Gold Extraction Technologies [J]. Gold Science and Technology, 2017, 25(4): 113-121.
[12]	TIAN Runqing，LIU Yunhua，TIAN Minmin，WEI Juzhen，TENG Fei，LI Huan，LI Xing. Mineral Processing Experiments on Fine-disseminated Gold Ore from Shaanxi Province [J]. Gold Science and Technology, 2016, 24(6): 102-106.
[13]	XIAO Li，LV Cuicui，WANG Yongliang，YE Shufeng. [J]. Gold Science and Technology, 2016, 24(5): 115-120.
[14]	YANG Junyan，GUO Hongzhu，CHEN Ping，XU Zhongmin. Application of Atmospheric Oxygen Enriched Leaching in Gold Cyanide Production [J]. Gold Science and Technology, 2016, 24(4): 160-163.
[15]	WANG Yongliang，LV Cuicui，XIAO Li，DING Jian，FU Guoyan，YE Shufeng. [J]. Gold Science and Technology, 2016, 24(4): 144-148.

Research Progress on Removal of Cyanide in Water by Adsorption

RichHTML

PDF (PC)

Abstract

Cite this article

share this article

Figures/Tables 2

References 0

Related Articles 15

Metrics

Comments

Recommended 10