Mineral Exploration and Resource Evaluation
Jinchang ZHONG, Yong ZHANG, Qian AN, Jie HUANG, Jiayong PAN, Xiaotian ZHANG, Shanchu HAN, Jie YAN, Siyuan ZHANG, Haotong DAI, Fumei WANG, Huayang JIANG, Haosai ZHANG, Junhao CHEN, Xia ZHANG
In recent years, substantial advancements have been achieved in lithium prospecting within the Altyn region, where exploration and research have identified a series of Caledonian spodumene pegmatite-type lithium deposits. Nonetheless, the metallogenic potential of Indosinian lithium, along with the mechanisms of lithium migration and enrichment in pegmatite-type lithium deposits, continues to be a subject of considerable scientific interest. The Kumusayi granite-pegmatite type lithium-beryllium deposit is classified as a medium-sized spodumene deposit, with the potential to reach a super-large scale. Its host rock is biotite schist, which exhibits significant hydrothermal alterations, such as greisenization, adjacent to the ore bodies. Through comprehensive field investigations and analytical techniques, including petrographic microscopy, electron probe microanalysis (EPMA), and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), the formation age of the lithium-ore-forming pegmatite has been established. Furthermore, the mineralogical composition of various mica types within the pegmatite and host rocks has been elucidated, and the migration and evolution patterns of rare metal elements, such as lithium, have been investigated. The U-Pb isotopic analysis of monazite from the Kumusayi lithium deposit indicates that the formation ages of the coarse-grained tourmaline-spodumene granite pegmatite and the muscovite granite pegmatite with inclusions are (224.6±3.0)Ma and (224.2±3.6)Ma, respectively. These findings suggest that the formation occurred during the Indosinian period. The investigation of mica minerals elucidates the magmatic-hydrothermal evolution process of the Kumusayi pegmatite-type lithium deposit. During the magmatic stage, the crystallization of spodumene significantly depleted the system’s lithium content, subsequently leading to the formation of lithium-bearing muscovite (magmatic-type). During the ensuing magmatic-hydrothermal alteration of the host rock, some lithium was leached from the host rock and re-precipitated to form lithium-rich muscovite (Li2O=1.8%~2.3%). In later stages (H2-H3), the muscovite continued to consume lithium from the hydrothermal fluid, culminating in the formation of low-lithium muscovite (Li2O=0.08%~0.15%) in the final stage. The study provides substantial evidence that the interplay between magmatic processes and hydrothermal activity is a critical factor in the enrichment and mineralization of lithium within muscovite-type lithium deposits. The determination of the Indosinian lithium mineralization age, along with insights into the detailed processes of lithium migration and enrichment during magmatic-hydrothermal events at the Kumusayi lithium deposit, offers new chronological data and exploration insights for lithium mineral exploration in the Altyn region.