铜镍冶炼渣的资源化利用研究进展

doi:10.11872/j.issn.1005-2518.2020.05.111

Abstract

Abstract:

Copper and nickel slag is an industrial by-product produced by smelting copper-nickel metal in smelters，and it is an urgent problem to comprehensively utilize copper nickel slag and realize the development and utilization of high value-added products.The microcrystalline glass with good mechanical properties and high corrosion resistance can be prepared by using copper-nickel slag as the main materials and adding a small amount of composition regulator，clarifier and co-solvent in the process of production.Copper and nickel slag contains a lot of valuable metals，so it can be recovered by means of solution leaching，flotation extraction and high temperature reduction.In addition，the method of physical and chemical excitation of copper and nickel slag can be used to prepare mine filling green cementitious materials and high strength composite cementitious materials under the condition of mineral admixtures.Moreover，copper and nickel slag can also be used for concrete fine aggregate.The resource utilization of copper and nickel slag can save resources and protect environment.Compared with flotation and high temperature reduction method recovery to extract valuable metals from nickel smelting slag，the chemical solution leaching treatment method can comprehensively recover valuable elements and realize the cascade utilization.And the small amount of iron compounds after removing iron from copper nickel slag can be used as nucleating agent in the preparation of microcrystalline glass，which would be greatly improved the utilization rate of industrial copper nickel waste slag.In additon，combined with the new concrete technology is the key to solving the disadvantages of high density and low activity of copper nickel slag in the application of civil engineering.Therefore，further research is needed to fully utilize copper and nickel slag on a large scale.

Key words: copper and nickel slag, resource utilization, chemical composition, mineral composition, valuable metals, cementitious materials

CLC Number:

TU526

Tingting ZHANG, Shiwei ZHI, Lijie GUO, Zhenlin WU, Junnan HAN. Research Progress of Resource Utilization of Copper-Nickel Smelting Slag[J].Gold Science and Technology, 2020, 28(5): 637-645.

Figures/Tables 7

Table 1

Composition of the copper and nickel slag"

化学成分/%											数据来源
$S i O 2$	$F e 2 O 3$	$A l 2 O 3$	$C a O$	$M g O$	$S O 3$	$N a 2 O$	$K 2 O$	$N i O$	$C u O$	$C r 2 O 3$	数据来源
32.37	53.87	1.18	1.66	6.53	1.00	0.56	-	0.54	0.49	0.43	文献[8]
26.75	60.63	2.63	2.73	3.61	1.00	0.25	0.60	0.43	0.51	-	文献[9]
34.60	50.20	3.20	2.20	5.30	0.60	0.60	0.40	-	-	-	文献[10]

Table 1

Fig.1

Fig.2

Table 2

Fig.3

Fig.4

Fig.5

References 39

1	余明江，胡梦楠，郭中鹏.高温处理对镍渣活性的影响及机理研究［J］.建材与装饰，2016（42）：58-59.
	Yu Mingjiang，Hu Mengnan，Guo Zhongpeng.Effect and mechanism of high temperature treatment on nickel slag activity ［J］.Construction Materials and Decoration，2016（42）：58-59.
2	Davidovits J.Global warming impact on the cement and aggregates industries［J］.World Resource Review，1994，6（2）：263-278.
3	周琦，南雪丽，易育强，等.镍渣微晶玻璃制备及铁的回收利用［J］.兰州理工大学学报，2010，36（5）：14-18.
	Zhou Qi，Xueli Nan，Yi Yuqiang，et al.Preparation of glass-ceramics with nickel slag and recovery of iron form nickel slag［J］.Journal of Lanzhou University of Technology，2010，36（5）：14-18.
4	赵青林，万利，康俊峰，等.富铁镍渣微晶玻璃及制备方法：CN201310557303.9［P］.2014-02-05.
	Zhao Qinglin，Wan Li，Kang Junfeng，et al.Fe-Ni-rich slag glass-ceramics and preparation methods：CN 201310557303.9［P］.2014-02-05.
5	李小明，沈苗，王翀，等.镍渣资源化利用现状及发展趋势分析［J］.材料导报，2017，31（5）：100-105.
	Li Xiaoming，Shen Miao，Wang Chong，et al.Current situation and development of comprehensive utilization of nickel slag［J］.Materials Reports，2017，31（5）：100-105.
6	杨志强，王永前，高谦，等.金川镍矿废弃物在充填采矿中利用现状与展望［J］.矿产综合利用，2017（3）：22-28.
	Yang Zhiqiang，Wang Yongqian，Gao Qian，et al.Present research situation and prospect of nickel utilization of wastes in filling mining technology in Jinchuan mine［J］.Multipurpose Utilization of Mineral Resources，2017（3）：22-28.
7	Cao Z M，Sun G S，Richter K，et al.Microstructre and metal distribution in Jichuan nickel smelting slag［J］.Journal of Beijing University of Science and Technology，2001，23（4）：316-319.
8	Zhang T T，Zhi S W，Li T，et al.Alkali activation of copper and nickel slag composite cementitious materials［J］.Materials，2020，13（5）：1155-1170.
9	Wang L J，Wei Y K，Lü G C，et al.Experimental studies on chemical activation of cementitious materials from smelting slag of copper and nickel mine［J］.Materials，2019，12（2）：303-314.
10	王国强，郭利杰，陈寅，等.喀拉通克铜镍矿充填胶凝材料基本性能研究［J］.中国矿业，2019，28（增1）：154-157.
	Wang Guoqiang，Guo Lijie，Chen Yin，et al.Study on basic properties of filling cementitious material in Kalatongke copper-nickle mine［J］.China Mining Magazine，2019，28（Supp.1）：154-157.
11	Bruckard W J，Somerville M，Hao F.The recovery of copper，by flotation，from calcium-ferrite-based slag made in continuous pilot plant smelting trials［J］.Minerals Engineering，2004，17（4）：495-504.
12	韩伟，秦庆伟.澳斯麦特熔炼渣回收铜实验研究［J］.铜业工程，2012，14（3）：8-10，14.
	Han Wei，Qin Qingwei.Experimental study on copper recovery from Au smelt slag［J］.Copper Engineering，2012 14（3）：8-10，14.
13	王珩.炼铜转炉渣中铜铁的选矿研究［J］.有色矿山，2003，32（4）：19-23.
	Wang Heng.Study on copper and iron concentrating from coverter slag of copper smelting［J］.Nonferrous Mines，2003，32（4）：19-23.
14	张宗涛.含少量镍、铜的铁红渣的综合利用［J］.云南化工，2002，29（5）：4-6.
	Zhang Zongtao.Comprehensive utilization of iron oxide slag containing trace amount of nickel and copper ［J］.Yunnan Chemical Technology，2002，29（5）：4-6.
15	Herreros O，Quiroz R，Manzano E，et al.Copper extraction from reverberatory and flash furnace slag copper extraction from reverberatory and flash furnace slag by chlorine leaching［J］.Hydrometallurgy，1998，49（1/2）：87-101.
16	邓彤，文震，刘东.硫酸介质中氯化物参与下氧化浸出铜渣过程［J］.中国有色金属学报，2001，11（2）：302-306.
	Deng Tong，Wen Zhen，Liu Dong.Leaching of copper residue with oxygen in sulfuric acid with participation of chloride［J］.The Chinese Journal of Nonferrous Metals，2001，11（2）：302-306.
17	Basir A S M，Rabah M A.Hydrometallurgical recovery of metal values from brass melting slag［J］.Hydrometallurgy，1999，53（1）：31-44.
18	朱丽芳.含铜镍浸出渣中铁铜镍的分离回收研究［D］.西安：西安建筑科技大学，2013.
	Zhu Lifang.Process of Separating and Recovering Copper，Nickel and Iron from Slag Containing Copper and Nickel［D］.Xi’an：Xi’an University of Architecture and Technology，2013.
19	吴道洪.直接还原—磨选处理铜渣及镍渣的炼铁方法：CN200910088663.2［P］.2009-12-02.
	Wu Daohong.Iron making method for direct reduction-grinding treatment of copper slag and nickel slag：CN200910088663.2［P］.2009-12-02.
20	彭朋，王爽，李克庆.镍渣提铁的深度还原—磁选试验研究［C］//第六届尾矿与冶金渣综合利用技术研讨会暨衢州市项目招商对接会论文集.北京：中国硅酸盐学会工艺岩石学分会，2015：101-107.
	Peng Peng，Wang Shuang，Li Keqing.Research on deep reduction-high efficient separation of nickel-copper slag［C］//Proceedings of the 6th Tailings and Metallurgical Slag Comprehensive Utilization Technology Seminar and Quzhou Project Investment Matching Meeting.Beijing：Technological Petrology Branch of The Chinese Ceramic Society，2015：101-107.
21	Zhou S W，Wei Y G，Li B，et al.Cleaner recycling of iron from waste copper slag by using walnut shell char as green reductant［J］.Journal of Cleaner Production，2019（217）：423-431.
22	张林楠，张力，王明玉，等.铜渣贫化的选择性还原过程［J］.有色金属，2005，57（3）：44-47.
	Zhang Linnan，Zhang Li，Wang Mingyu，et al.Research on selective reducing impoverishment process of copper slag［J］.Nonferrous Metals，2005，57（3）：44-47.
23	南雪丽，卢学峰，傅希圣.利用复合工业废渣制备CaO-MgO-Al₂O₃-SiO₂微晶玻璃［J］.有色金属，2011，63（1）：118-122.
	Xueli Nan，Lu Xuefeng，Fu Xisheng.Preparation of glass-ceramics of CaO-MgO-A1₂O₃-SiO₂ with composite industrial residue［J］.Nonferrous Metals，2011，63（1）：118-122.
24	王亚利，倪文，马明生，等.金川镍渣熔融炼铁及熔渣制备微晶玻璃的研究［J］.矿产保护与利用，2008（2）：55-58.
	Wang Yali，Ni Wen，Ma Mingsheng，et al.Iron mell-reduction from nickel slag and preparation of glass-ceramics from its molten slag［J］.Conservation and Utilization of Mineral Resources，2008（2）：55-58.
25	徐彬，蒲心诚.碱矿渣水泥混凝土研究进展及其发展前景［J］.材料导报，1998，12（4）：41- 43.
	Xu Bin，Pu Xincheng.Development and future of AAS cement and concrete［J］.Materials Reports，1998，12（4）：41-43.
26	Wang S D，Scrivener K L.Hydration products of alkali activated slag cement［J］.Cement and Concrete Research，1995，25（3）：561-571.
27	蒲心诚，甘昌成，吴礼贤，等.碱矿渣（JK）混凝土的性能［J］.硅酸盐通报，1989（5）：5-11.
	Pu Xincheng，Gan Changcheng，Wu Lixian，et al.Properties of alkali slag（JK） concrete［J］.Bulletin of the Chinese Ceramic Society，1989（5）：5-11.
28	Rashad A M.A comprehensive overview about the influence of different additives on the properties of alkali-activated slag—A guide for Civil Engineer［J］.Construction and Building Materials，2013，47：29-55.
29	Fernández-Jimenez A，Palomo J G，Puertas F.Alkali-activated slag mortars：Mechanical strength behavior［J］.Cement and Concrete Research，1999，29（8）：1313-1321.
30	Puertas F，González-Fonteboa B，González-Taboada I，et al.Alkali-activated slag concrete：Fresh and hardened behaviour［J］.Cement and Concrete Composites，2018（85）：22-31.
31	杨志强，高谦，王永前，等.利用金川水淬镍渣尾砂开发新型充填胶凝剂试验研究［J］.岩土工程学报，2014，36（8）：1498-1506.
	Yang Zhiqiang，Gao Qian，Wang Yongqian，et al.Experimental study on new filling cementing material using water-hardening nickel slag tailings of Jinchuan mine［J］.Chinese Journal of Geotechnical Engineering，2014，36（8）：1498-1506.
32	李文臣，郭利杰，杨超，等.碱激发铜镍水淬冶炼渣制备充填胶凝材料研究［J］.中国矿业，2020，29（7）：122-127.
	Li Wenchen，Guo Lijie，Yang Chao，et al.Study on filling cementitious materials by alkali-activated water quenched copper-nickel smelting slag［J］.China Mining Magazine，2020，29（7）：122-127.
33	诸华军，吴其胜，周阳，等.镍矿渣地聚合物的制备及其增韧改性［J］.硅酸盐通报，2017，36（7）：2321-2325.
	Zhu Huajun，Wu Qisheng，Zhou Yang，et al.Preparation and toughening modification of nickel slag-blast furnace slag geopolymers［J］.Bulletin of the Chinese Ceramic Society，2017，36（7）：2321-2325.
34	单昌峰，王键，郑金福，等.镍渣在混凝土中的应用研究［J］.硅酸盐通报，2012，31（5）：1263-1268.
	Shan Changfeng，Wang Jian，Zheng Jinfu，et al.Study on application of nickel slag in cement concrete［J］.Bulletin of the Chinese Ceramic Society，2012，31（5）：1263-1268.
35	李浩，杨鼎宜，沈武，等.掺镍渣对混凝土耐磨性能的影响研究［J］.硅酸盐通报，2015，34（11）：3122-3128.
	Li Hao，Yang Dingyi，Shen Wu，et al.Effect of nickel slag to wear resistance of concrete［J］.Bulletin of the Chinese Ceramic Society，2015，34（11）：3122-3128.
36	朱恩欢，林云腾，龚涵，等.高炉镍铁渣粉对混凝土性能的影响［J］.混凝土与水泥制品，2017（12）：97-99.
	Zhu Eenhuan，Lin Yunteng，Gong Han，et al.Effect of blast furnace Ni-Fe slag powder on concrete performance［J］.China Concrete and Cement Products，2017（12）：97-99.
37	孟渊，田斌守，邵继新，等.利用冶炼工业废弃物镍渣研制混凝土储热材料［J］.混凝土与水泥制品，2015 （2）：93-95.
	Meng Yuan，Tian Binshou，Shao Jixin，et al.Concrete heat storage material developed by using nickel slag from smelting industry［J］.China Concrete and Cement Products，2015（2）：93-95.
38	陈寅，郭利杰，邵亚平，等.喀拉通克铜镍矿充填骨料优化试验［J］.有色金属（矿山部分），2018，70（6）：38-41.
	Chen Yin，Guo Lijie，Shao Yaping，et al.Experimental optimization of filling aggregates in Kalatongke copper-nickel mine［J］.Transactions of Nonferrous Metals Society of China（Mining Section），2018，70（6）：38-41.
39	王国强，郭利杰，陈寅，等.喀拉通克铜镍矿充填胶凝材料基本性能研究［J］.中国矿业，2019，28（增1）：154-157.
	Wang Guoqiang，Guo Lijie，Chen Yin，et al.Study on basic properties of filling cementitious material in Kalatongke copper-nickle mine［J］.China Mining Magazine，2019，28（Supp.1）：154-157.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed

Comments

Recommended 10

[1]	YANG Bao-Rong, YANG Xiao-Bin. Geological Characteristics and Ore-Controlling Factors of the Guoluolongwa Gold deposit，Doulan County，Qinghai Province[J]. J4, 2007, 15(1): 26 -30 .
[2]	. [J]. Gold Science and Technology, 0, (): 0 .
[3]	DUAN Liuan,QI Jingjie,Dun Meixia. Geological Characteristics and Ore-Searching Direction of Zhongzhuang Gold Deposits in Rushan City，Shangdong Province[J]. J4, 2007, 15(6): 24 -29 .
[4]	DUAN Liu-An, DIAO Meng-Chuan, WANG Zhi-Jun. Metallogenic Regularities and Prospecting Analysis ofXilaokou Ore Area in Rushan[J]. J4, 2009, 17(3): 31 -34 .
[5]	HAN Ge-Qi, HU Ji-Feng, LIU Hua-Dong, LIU Yin-Zhi, MEI Wen-Ze, CAO Ji-Jian. [J]. J4, 1999, 7(4~5): 55 -58 .
[6]	ZHANG Wen-Zhao, XU Shu-Beng. Gold Metallogenic Features and Prospecting Targets of the Zhao-ping Fault Zone[J]. J4, 2006, 14(2): 1 -10 .
[7]	HUANG Zhongjun,WANG Guichun,GAO Rong. The Geological Characteristics and Prospecting of Ajile Gold and Ploymetallic Mine in Dongwuqi , Inner Mongolia[J]. J4, 2011, 19(3): 22 -29 .
[8]	XU Huan，DOU Hongwei，ZHANG Zhenghu，ZHANG Zhiqiang. The Geological Features of Prospecting Indicator in Elashankou Silver-Lead-Zinc Deposit,Qinghai Province[J]. J4, 2012, 20(1): 71 -77 .
[9]	CHEN Fangfang,ZHANG Yifei,XUE Guang. Disposal to Pollution and Resource Utilization to Waste for Gold Smelting[J]. J4, 2011, 19(2): 67 -73 .
[10]	SUN Huanying,LI Yongsheng. Significance and Development Trends of Geological Prospecting Informatization[J]. Gold Science and Technology, 2013, 21(2): 65 -68 .

物相	拟合	混合样	原样
玻璃相	0	24.82	27.58
铁镁橄榄石	86.70	65.18	72.42
氧化锌	13.30	10.00	0.00

Research Progress of Resource Utilization of Copper-Nickel Smelting Slag

RichHTML

PDF (PC)

Abstract

Cite this article

share this article

Figures/Tables 7

References 39

Related Articles 7

Metrics

Comments

Recommended 10

[1]	Zhiyuan YE,Qianqian WANG. Preparation and Performance of Aluminosilicate Based Solid Waste Cemen-titious Materials [J]. Gold Science and Technology, 2020, 28(5): 658-668.
[2]	Lijie GUO, Lei ZHANG, Wenchen LI. Progress and Prospects of the Preparation of Cementitious Materials Based on Nonferrous Metallurgical Slags [J]. Gold Science and Technology, 2020, 28(5): 621-636.
[3]	Wenping ZHANG, Mingming CAI, Chao XU. Process Mineralogy of a Gold-bearing Primary Ore [J]. Gold Science and Technology, 2019, 27(5): 770-776.
[4]	WANG Fulin，MIN Chendi. Research and Application of Resource Utilization of Primary Lead Smelting Slag [J]. Gold Science and Technology, 2017, 25(6): 127-132.
[5]	ZHANG Shugen，LIU Xuan，LIU Chunbo，HUANG Chaowen. The Morphological and Chemical Characteristics of Gold Minerals and Their Ore Genetic Significances in Xinshan Gold Deposit，Yunnan Province [J]. Gold Science and Technology, 2016, 24(4): 1-9.
[6]	CHEN Fangfang,ZHANG Yifei,XUE Guang. Disposal to Pollution and Resource Utilization to Waste for Gold Smelting [J]. J4, 2011, 19(2): 67-73.
[7]	TIAN Hong-Wei, FU Cai-Yun, ZHANG Bao-Ren. Resource Evaluation of Explosion Breccia-type Gold Deposit in Qiyugou Area [J]. J4, 2010, 18(1): 6-10.