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J4 ›› 2010, Vol. 18 ›› Issue (5): 123-124.

• 矿产勘查 • 上一篇    

X 射线荧光光谱法测定铁矿石中主次成分

罗学辉,陈占生,陈雪,李玄辉   

  1. 武警黄金地质研究所,河北  廊坊  065000
  • 收稿日期:2010-03-24 修回日期:2010-09-15 出版日期:2010-10-28 发布日期:2012-05-23
  • 作者简介:罗学辉(1979-),男,内蒙古乌兰察布人,工程师,主要从事X 荧光光谱分析及矿物分析工作.LS19760811@sohu.com

Determination of Main and Minor Components in Iron Ores by X-ray Spectormetry

LUO Xuehui,CHEN Zhansheng,CHEN Xue,LI Xuanhui   

  1. Gold Geological Institute of CAPF,Langfang 065000,Hebei,China
  • Received:2010-03-24 Revised:2010-09-15 Online:2010-10-28 Published:2012-05-23

摘要:

采用四硼酸锂和偏硼酸锂,氟化锂[m(Li2B4O7)∶m(LiBO2)∶m(LiF)=4.5∶1∶0.4]为熔剂,采用1∶30 熔剂稀释比,于1 050 ℃熔融铁矿样品制成玻璃样片,用波长色散X 射线荧光光谱仪同时对样片中Fe、Si、Al、Mg、Ca、Na、K、P 进行测定。用铁矿石标样经同法测定并对测定结果进行理论a 系数校正后绘制工作曲线。10 次制样测量各组分,相对标准偏差在0.43%~5.86%范围内,该方法与化学测定结果符合较好,完全满足日常分析的需要。

关键词: X 射线荧光光谱, 铁矿石, 熔融玻璃片

Abstract:

The samples were made into a glass melting piece at 1 050 ℃ with [m(Li2B4O7)∶m(LiBO2)∶m(LiF)=4.5∶1∶0.4] as flux at a dilution of 1∶30.The elements includingFe、Si、Al、Mg、Ca、Na、K、P in the melting piece were simultaneously determined by X-ray spectrometry.The calibration curve was carried out with the standard samples. Whose determination results obtained by X-ray fluorescence were calibrated with a theoretical a-coefficient.Results obtained by the method were in good accordance with those values determined by chemical methods.Relative standard deviation(n=10)for each component were in the range of 0.43%~5.86%.

Key words: X-ray spectormetry, Iron ores, Fusion beads

中图分类号: 

  • O657.34

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[1] 罗学辉,王春生,陈占生,张勇. 粉末压片—波长色散X 射线荧光光谱法在钼矿石测定中的应用[J]. J4, 2011, 19(2): 78-80.
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