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黄金科学技术 ›› 2023, Vol. 31 ›› Issue (1): 15-25.doi: 10.11872/j.issn.1005-2518.2023.01.043

• 矿产勘查与资源评价 • 上一篇    下一篇

滇西北燕山期含矿花岗岩与全球埃达克岩地球化学特征对比

曹振梁1(),刘学龙1(),李守奎1,2,刘思晗1,李方兰1,周博文1   

  1. 1.昆明理工大学国土资源工程学院,云南 昆明 650093
    2.云南省地质矿产勘查院,云南 昆明 650051
  • 收稿日期:2022-03-18 修回日期:2022-09-08 出版日期:2023-02-28 发布日期:2023-03-27
  • 通讯作者: 刘学龙 E-mail:815308803@qq.com;xuelongliu@foxmail.com
  • 作者简介:曹振梁(1997-),男,黑龙江双鸭山人,硕士研究生,从事地球化学研究工作。815308803@qq.com
  • 基金资助:
    云南黄金集团校企合作项目“滇西北中甸地区红牛—红山铜矿叠加成矿机理及矿床模型研究”(KKF0202121292);云南省顶尖团队专项“香格里拉格咱—麻花坪地区W-Be等战略矿产形成机理及资源潜力评价”(202205AT350004);昆明理工大学“双一流”科技专项课题“薄竹山燕山晚期岩浆成矿系统及成矿规律研究”(202202AG050006);国家自然科学基金项目“滇西北中甸铜厂沟燕山期斑岩型Mo-Cu矿床热液蚀变分带结构及发育机制”(41862009)

Comparison of Geochemical Characteristics Between Yanshanian Ore-bearing Granites in Northwest Yunnan and Global Adakites

Zhenliang CAO1(),Xuelong LIU1(),Shoukui LI1,2,Sihan LIU1,Fanglan LI1,Bowen ZHOU1   

  1. 1.Faculty of Land Resources Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China
    2.Yunnan Institute of Geology and Mineral Resources Exploration, Kunming 650051, Yunnan, China
  • Received:2022-03-18 Revised:2022-09-08 Online:2023-02-28 Published:2023-03-27
  • Contact: Xuelong LIU E-mail:815308803@qq.com;xuelongliu@foxmail.com

摘要:

为便于下一步找矿勘查研究,在前人研究基础上,收集并整理滇西北燕山期含矿岩体地球化学数据,结合现有研究成果,对滇西北地区进行整体性研究。根据数据筛选原则,绘制置信椭圆,计算相应交叠率,采用大数据方法,计算不同元素对比值,与全球埃达克岩对比,共获得图件65 536个。研究表明:燕山期岩体具有全球埃达克岩属性但又有其自身特点。某些元素比值(含Mo、Cu)较小且超出了全球埃达克岩的范围,说明Mo和Cu元素在该地区燕山期岩体中占据主导因素,富集程度较好。在K2O/Mo-SiO2/Cu、Na2O/Cu-SiO2/Mo、MnO/Cu-SiO2/Cu和Na2O/Zn-SiO2/Mo等图件中,Mo、Cu元素与SiO2、TiO2、K2O、Na2O等拟合程度较好,具有一致的变化趋势,另外斑岩铜钼矿含矿流体作用和矿化作用不断演化,燕山期与含矿有关的花岗岩数据点偏离全球埃达克岩分布范围越远,其逸出程度也越大。该区燕山期含矿岩体与埃达克岩具有相似的产出背景,将埃达克岩的相关研究应用于该区,有助于进一步指导地质工作。

关键词: 燕山期花岗岩, 埃达克岩, 地球化学, 数据挖掘, 大数据方法, 置信椭圆, 滇西北

Abstract:

Sanjiang area in southwest China is an important area for geological research.On the basis of previous studies,through collecting and collating the geochemical literature related to Yanshanian deposits in the Geza island arc,418 representative geochemical data of ore-bearing rock masses in the area were obtained,including Xiuwacu tungsten-molybdenum deposit,Tongchanggou molybdenum-copper deposit,Relin molybdenum-tungsten-copper deposit,Hongshan copper-molybdenum deposit and Hongniu copper-molybdenum deposit.Combined with computer big data,referring to previous research methods and according to the principle of data screening,the data with SiO2 content greater than 56% and less than 90%(granite SiO2>56%) were retained during screening.Excluding data with H2O and LOI content greater than 7% and CO2 content greater than 3%(high H2O and LOI content indicates strong alteration; high CO2 content indicates strong carbonation and calcitization). Remove some samples with abnormally high content of main elements,such as samples with Fe2O3>30% and abnomally high MnO content.Remove the data with abnormally high trace elements(sample retention).Draw the confidence ellipse and calculate the corresponding overlap rate.Meanwhile,the abnormal values in the study area(such as abnormal high values,abnormal low values,20 times higher than the average value of sample elements,etc.) were deleted during the study,the sample was retained and the negative value(which may exceed the detection limit) was deleted.The big data method was used to calculate the comparison values of different elements,and 65 536 maps were obtained by comparing with the global adakites.The study shows that the Yanshanian rock mass has the global adakite attribute,but also has its own characteristics.Some element ratios (the denominator contains Mo and Cu) are small and exceed the range of global adakite,which indicates that Mo and Cu elements dominate the Yanshanian rock mass in this area and the enrichment degree is good.In maps such as K2O/Mo-SiO2/Cu,Na2O/Cu-SiO2/Mo,MnO/Cu-SiO2/Cu,Na2O/Zn-SiO2/Mo,Mo and Cu fit well with most elements such as SiO2,TiO2,K2O and Na2O,and have the same trend of change,which indicates that the ore-bearing fluid and mineralization of Mo and Cu porphyry copper molybdenum ore are evolving continuously.The farther the Yanshanian granite data points related to ore-bearing deviate from the global adakite distribution range,the greater the escape degree.The Yanshanian ore-bearing rock mass in this area has a similar occurrence background to adakites.The application of relevant research on adakites in this area can further guide geological work.

Key words: Yanshanian granite, adakite, geochemistry, data mining, big data method, confidence ellipse, northwest Yunnan

中图分类号: 

  • P618.5

图1

滇西北区域地质图(修改自刘学龙等,2021b;年龄数据来自王新松等,2011;孟健寅,2014;余海军等,2015)Ⅰ-扬子板块;Ⅱ-甘孜—理塘板块结合带;Ⅲ-义敦岛弧带;Ⅳ-中咱微陆块;Ⅴ-金沙江结合带;Ⅵ-江达—维西火山弧;Ⅶ-昌都—兰坪陆块;Ⅷ-三达山—景洪火山弧;Ⅸ-澜沧江结合带;Ⅹ-保山地块"

表1

滇西北燕山期含矿岩体地球化学数据统计"

序号矿区名称数据数量/个岩石类型文献来源
1休瓦促矿区212似斑状黑云母花岗岩、二长花岗岩、黑云母花岗岩、斑状二长花岗岩、花岗斑岩、黑云母花岗斑岩、花岗二长斑岩、白钨矿和矿化花岗斑岩

刘学龙,2009孟健寅,2014余海军等,2016

张向飞等,2017张向飞,2018王忠强等,2020陈莉等,2020

2热林矿区41花岗闪长斑岩、闪长玢岩和中粒似斑状二长花岗斑岩刘学龙,2009尹光候等,2009伍建兢等,2011孟健寅,2014杨富成等,2017谈荣钰等,2018
3红山—红牛矿区76石英二长斑岩、闪长玢岩、花岗斑岩和石英闪长玢岩

黄肖潇等,2012彭惠娟,2014孟健寅,2014

王鹏,2016余海军,2018

4铜厂沟矿区89花岗闪长斑岩、钾化花岗闪长斑岩、绢英岩化花岗闪长斑岩、青磐岩化花岗闪长斑岩和辉钼矿化花岗闪长斑岩彦廷龙等,2016姚雪等,2017Yang et al.,2017He et al.,2018谈荣钰等,2018Liu et al.,2019李守奎等,2021

图2

全球埃达克岩包含燕山期花岗岩数据散点图注:蓝色为全球埃达克岩数据,红色为燕山期花岗岩数据"

图3

燕山期花岗岩包含全球埃达克岩数据散点图注:蓝色为全球埃达克岩数据,红色为燕山期含矿岩体地球化学数据"

图4

燕山期花岗岩与全球埃达克岩数据Pb/Cu-SiO2/Co解析图注:蓝色为全球埃达克岩数据,红色为燕山期花岗岩数据,黑色为二者重叠部分,黄色箭头表示蚀变作用和逸出趋势"

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