Treatment of Cyanide Wastewater by Chemical Precipitation-Electric Adsorption
Received date: 2015-05-03
Revised date: 2015-06-29
Online published: 2015-11-16
Treatment of gold mine wastewater with the characteristics of cyanide,high copper,iron by the chemical precipitation-electric adsorption combined technology,the analyzed and discussed were focused on the reaction principle,the technological process and the result of the reaction.Research shows that the method is viable to treatment wastewater containing high concentration of cyanide.After precipitation by ZnSO4,the precipitation rate of free cyanide,Fe and Cu in wastewater were 100%,85.89% and 99.43%,respectively.After advanced treatment by electric adsorption,the removal rates of Cu,thiocyanate,and free cyanide were 98.68%,43.60% and 99.57%,respectively.The XRD analysis showed that the sediment from zinc sulfate precipitate mainly includes Zn2[Fe(CN)6],Zn(CN)2 and CuCN,and the sediment from the electric adsorption is mainly CuSCN.Sediment and the anode plate after saturated adsorption can be comprehensive treatment and recovery of cyanide and metal,and the wastewater can be returned to the leaching system for recycling at the same time.
Key words: cyanide wastewater; ZnSO4; chemical precipitation; electric adsorption
SONG Yonghui , LEI Siming , ZHOU Jun . Treatment of Cyanide Wastewater by Chemical Precipitation-Electric Adsorption[J]. Gold Science and Technology, 2015 , 23(4) : 75 -79 . DOI: 10.11872/j.issn.1005-2518.2015.04.075
[1] 邢相栋,兰新哲,宋永辉,等.氰化法提金工艺中“三废”处理技术[J].黄金,2008,29(12):55-61.
[2] 鲁建丰.黄金冶炼废水铜的萃取回收[J].有色冶金设计与研究,2012,33(4):11-13.
[3] 孙建伟,刘青.黄金冶炼废水处理及有价金属回收[J].黄金科学技术,2015,23(2):94-97.
[4] Parga J R,Shukla S S,Carrillo Pedroza F R.Destruction of cyanide waste solutions using chlorine dioxide,ozone and titania sol[J].Waste Management,2003,23(2):183-191.
[5] White D M,Pilm T A,Woolard C.Biological treatment of cyanide containing waste water[J].Water Research,2000,34(7):2105-2109.
[6] Oliver T M,Jugoslav K,Aleksandar P,etal.Synthetic activa-ted carbons for the removal of hydrogencyanide from air[J].Chemical Engineering and Processing:Process Intensification,2005,44(11):1181-1187.
[7] Feng X,Dreisinger D.Studies on solvent extraction of copper and cyanide from waste cyanide solution[J].Journal of Hazardous Materials,2009,169(1/3):333-338.
[8] Dai X,Breuer P L,Jeffrey M I.Comparison of activated carbonand ion-exchange resins in recovering copper from cyanide leach solutions[J].Hydrometallurgy,2010,101(1/2):48-57.
[9] Depci T.Comparison of activated carbon and iron impregnated activated carbon derived from Gǒlbas lignite to remove cyanide from water[J].Chemical Engineering Journal,2012,181/182:467-478.
[10] Dai X W,Simons A,Breuer P.A review of copper cyanide recovery technologies for the cyanidation of copper containing gold ores[J].Minerals Engineering,2012,25(1):1-13.
[11] 李昌斌.工业废水化学处理过程建模与仿真研究[D].北京:北京化工大学,2012.
[12] 屈学化.沉淀法综合处理高铜提金氰化废水的研究[D].西安:西安建筑科技大学,2013.
[13] 淮敏超.高铜高硫氰根氰化提金尾液综合处理实验研究[D].西安:西安建筑科技大学,2013.
[14] 陈兆林,宋存义,孙晓慰,等.电吸附除盐技术的研究与应用进展[J].工业水处理,2011,31(4):11-14.
[15] 段小月,常立民,王昕瑶.活性炭电极对不同阳离子电吸附行为的研究[J].水处理技术,2010,36(4):32-35.
[16] Alfarra A,Frackowiak E,Béguin F.Mechanism of lithum electro-sorption by activated carbons[J].Electrochimica Acta,2002,47(3):1545-1553.
[17] Abbas A.Adsorption and electrosorption of nitrate and nitrite on high-area carbon cloth:an approach to purification of water and waste-water samples[J].Carbon,2003,41(6):1320-1322.
[18] 宋永辉,兰新哲,何辉.提金氰化废水处理理论与方法[M].北京:冶金工业出版社,2015:36-37.
[19] 宋永辉,屈学化,吴春晨,等.硫酸锌沉淀法处理高铜氰化废水的研究[J].稀有金属,2015,39(4):357-364.
[20] 李延霞.煤基电极材料制备及其在提金尾液治理中的应用[D].西安:西安建筑科技大学,2013.
[21] 宋永辉,李延霞,史军伟,等.煤基成型活性炭活化实验研究及性能表征[J].材料导报,2014,28(10):25-28.
[22] Song Y H,Lei S M,Wu C C,et al.Treatment cyanide-extracting gold wastewater by adsorption and electric adsorption[C]//4th ICEEP,2015,Shenzhen,China:DEStech Publications,2015.
/
〈 |
|
〉 |