Research on Acidic Oxidation Pretreatment of Arsenic and Sulfur-bearing Gold Concentrate at Tianmashan Mine,Tongling
Received date: 2014-12-26
Revised date: 2015-02-03
Online published: 2015-11-16
Gold cyanide leaching for a arsenic and sulfur-bearing gold concentrate at Tianmashan,Tongling,was difficult due to the fine disseminated grain sizes and large amounts of the gold mineral wrapped by sulfides.In order to improve the efficiency of cyanide leaching,some of tests regarding acidic oxidation pretreatment in the systems of HCl-H2O2-addictive were carried out under the conditions that the proportion of grinding fineness at -0.048 mm was 90%,pulp density at 40 g/L,stirring speed at 400 r/min,reaction temperature at 60 ℃,reaction time at 4 h,dosage of HCl at 0.7 mol/L,dosage of H2O2 at 0.5 mol/L and dosage of ethylene glycol at 9 mL/L.As a result,the dissolution rates of iron,arsenic and copper were 48.1%,99.3% and 89.76%,respectively.What’s more,the leaching rate of cyanide leached gold increased 33.6% than that of cyanide leached directly after oxidation pretreatment to gold concentrate.It was evident that the crystal structure of sulfide was destructed after oxidation pretreatment,meanwhile,the As,Cu and other ingredients were dissolved.Thus,the gold cyanide leaching rate increased.Finally,some guidance for other similar arsenic and sulfur-bearing refractory gold concentrate processing is provided,which is expected to be meaningful for applicability and development of the oxidation pretreatment with the HCl-H2O2-ethylene glycol.
MA Yingqiang , HUANG Falan , YIN Wanzhong , HONG Jongsu . Research on Acidic Oxidation Pretreatment of Arsenic and Sulfur-bearing Gold Concentrate at Tianmashan Mine,Tongling[J]. Gold Science and Technology, 2015 , 23(3) : 83 -88 . DOI: 10.11872/j.issn.1005-2518.2015.03.083
[1] 钟俊.非氰浸金技术的研究及应用现状[J].黄金科学技术,2011,19(6):57-61.
[2] 孟宇群,吴敏杰,宿少玲,等.难浸金矿常温常压强化碱浸预处理新工艺研究[J].有色金属工程,2003,55(1):43-47.
[3] 沈述保,唐明刚.含砷金矿浮选的研究进展[J].黄金科学技术,2014,22(2):63-66.
[4] 杨华明,邱冠周,张和平.搅拌磨机械化学氰化浸金新工艺的研究[J].黄金,1998,19(4):36-38.
[5] 夏光祥,段东平,周娥,等.加压催化氧化氨浸法处理坪定金矿的研究和新工艺开发[J].黄金科学技术,2013,21(5):93-96.
[6] 涂博,张亚辉,尤大海,等.难处理金矿非氰提金方法研究现状[J].贵金属,2013,34(4):73-81.
[7] 伍赠玲.高砷难处理金精矿焙烧—氰化浸出工艺研究[J].矿产综合利用,2006,(6):16-18.
[8] 李云,王云,袁朝新,等.提高含砷金精矿两段焙烧焙砂中金浸出率的研究[J].有色金属:冶炼部分,2010,(6):33-36.
[9] 李大江.含砷金精矿的酸性热压氧化预处理试验[J].有色金属:冶炼部分,2011,(8):28-31.
[10] 黄中省,伍赠玲,邹刚,等.低品位难处理金矿生物氧化—氰化提金试验研究[J].有色冶金设计与研究,2012,33(3):1-4.
[11] 彭志成.难处理含金硫砷精矿氧化焙烧—碘化法浸出试验研究[D].衡阳:南华大学,2014.
[12] Jha M C.Refractoriness of certain gold ores to cyanidation:Probable causes and possible solutions[J].Mineral Processing and Extractive Metallurgy Review,1987,2(4):331-352.
[13] DemopoulosG P, Papamgelakis V G.Recent advances in refractory gold processing[J].CIM Bull,1989,82:85-91.
[14] 洪正秀,印万忠,马英强,等.某难氰化金精矿氧化预处理试验研究[J].金属矿山,2012,(4):79-82.
/
〈 | 〉 |