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Gold Science and Technology ›› 2018, Vol. 26 ›› Issue (4): 481-491.doi: 10.11872/j.issn.2095-4050.000000000000

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Characteristics of Pyrite from Huaishuping Gold Deposit in Xiong’ershan District and Its Geological Significance

Leilei ZHANG1,Jing ZHANG1(),Qisong WANG1,Liang CHEN2,Xu’an CHEN1   

  1. 1School of Earth Sciences and Resources，China University of Geosciences，Beijing 100083，China
    2Minmetals Exploration & Development Co.，Ltd.，Beijing 100010，China
  • Received:2018-04-18 Revised:2018-07-07 Online:2018-08-31 Published:2018-10-17

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Abstract:

Huaishuping gold deposit is located in the Xiong’ershan district，southern margin of the North China Craton.It is hosted by the Mesoproterozoic volcanic rocks of Xiong’er Group.The occurrence of gold orebodies is controlled by faults.Its ore types are altered rock and quartz vein，and the major metal minerals are pyrite，galena，sphalerite and chalcopyrite.The hydrothermal ore-forming process can be divided into three stages：quartz-pyrite vein （early），quartz-polymetallic vein （middle） and quartz-calcite vein （late）.In the early stage，pyrites are euhedral granular，with size of 0.8~2.0 mm；in the middle stage，they are subhedral and xenomorphic granular of 0.30~0.45 mm；and in the late stage，pyrite is euhedral-subhedral granular，and the particle size is 0.1~3.0 mm.The electron microprobe analysis showed that S element content in the pyrite was 51.25%~52.71%，and Fe element content was 45.78%~48.11%.The Cu，Zn and Sb elements content of pyrites in the middle stage were 0.108%，0.131% and 0.115% respectively.TheδFe andδS plot of major elements and the Co-Ni-As triangular diagram of pyrites study shows that the source of ore-forming fluid in Huaishuping gold deposit is medium-low temperature metamorphic hydrothermal fluid.

Key words: pyrite, typomorphic characteristics, electron microprobe, Huaishuping gold deposit, Xiong’ershan district, western Henan

CLC Number: 

  • P618.51

Fig.1

Tectonic location（a） and geological map （b） of Xiong’ershan region（modified by reference[11]）"

Fig.2

Geological map of Huaishuping gold deposit（modified by reference[12]"

Fig.3

Characteristics of ore samples in Huaishuping gold deposit"

Fig.4

Characteristics of pyrite in different levels and different mineralization stages"

Fig.5

Microscope characteristics of common ore minerals and texture features in Huaishuping gold deposit"

Fig.6

Paragenetic sequence of major minerals in Huaishuping gold deposit"

Fig.7

Pyrite crystal morphology of Huaishuping gold deposit in different mineralization stages under binocular microscope"

Table 1

Composition of pyrite detected by electron microprobe（%）"

样品编号 成矿阶段 海拔标高/m S Fe Co Ni Cu Zn As Se Ag Sb Te 总和
HSPD06B11-1 早 465 52.16 47.04 - 0.02 0.09 0.17 0.06 - 0.25 0.24 0.10 100.13
HSPD06B11-2 早 465 52.67 47.32 0.21 0.05 - 0.09 - 0.03 0.07 0.04 0.05 100.53
HSPD06B11-3 早 465 51.41 47.20 0.06 0.03 - 0.39 0.09 0.01 0.05 0.09 0.10 99.43
HSPD06B12-1 早 465 52.06 48.11 0.23 - 0.30 0.10 - - - - - 100.80
HSPD06B12-2 早 465 51.87 47.39 0.16 - 0.13 - - - - - - 99.55
HSPD06B12-3 早 465 52.12 47.42 - 0.06 - 0.28 - 0.07 0.14 - - 100.09
HSPD06B12-4 早 465 52.15 47.71 0.25 - - - 0.14 0.01 0.08 - 0.13 100.47
HSPD06B12-5 早 465 51.91 47.97 0.07 - - 0.14 - 0.06 - - - 100.15
HSPD06B13-1 早 465 51.32 47.10 0.24 - 0.33 0.05 - - - 0.28 0.02 99.34
HSPD06B13-2 早 465 51.59 47.71 0.34 0.12 0.13 - 0.23 0.18 0.12 - - 100.42
HSPD06B13-3 早 465 51.47 47.65 0.29 0.06 - - 0.06 0.04 - - - 99.57
HSPD06B06-1 中 465 51.58 47.08 - 0.16 0.03 0.12 0.03 0.03 - 0.13 - 99.16
HSPD06B06-3 中 465 51.69 46.87 0.16 0.13 0.21 0.12 - - - 0.14 - 99.32
HSPD06B06-4 中 465 52.06 47.29 0.07 - 0.13 - - - 0.12 - - 99.67
HSPD06B06-5 中 465 51.54 46.67 0.15 0.31 0.12 - - - - 0.17 0.05 99.01
HSPD06B06-6 中 465 51.99 47.25 0.09 0.22 0.20 0.64 - - - 0.25 0.04 100.68
HSPD16B01-1 中 570 51.58 47.39 0.24 0.11 0.20 - - - 0.27 - - 99.79
HSPD16B01-2 中 570 52.01 47.35 - 0.07 - - 0.02 0.11 0.17 0.13 0.25 100.11
HSPD16B01-3 中 570 51.64 47.36 0.07 0.18 - 0.01 0.10 0.02 0.04 - - 99.42
HSPD16B01-4 中 570 51.34 47.53 - 0.17 0.09 0.62 - 0.07 0.02 0.11 0.15 100.10
HSPD16B01-5 中 570 51.82 47.74 0.04 0.07 0.18 0.26 0.01 0.14 - 0.05 0.09 100.40
HSPD18B01-1 中 570 51.98 47.67 0.14 0.32 - 0.07 - - 0.21 - - 100.39
HSPD18B01-2 中 570 51.59 48.09 - - 0.11 - - - 0.01 - 0.08 99.88
HSPD18B01-3 中 570 52.02 47.51 0.15 0.17 - - - - - 0.04 0.33 100.22
HSPD20B01-1 晚 520 52.07 47.48 0.28 0.19 - - 0.11 0.14 0.06 - - 100.33
HSPD20B01-2 晚 520 52.71 47.33 0.28 0.07 - - 0.04 - 0.20 0.18 0.30 101.11
HSPD20B01-3 晚 520 51.25 46.80 - 0.05 0.01 0.11 - - - - - 98.22
HSPD20B01-4 晚 520 51.58 47.13 0.23 0.09 - - - - - 0.28 0.01 99.32

Table 2

Co，Ni，As content（%），δFe，δS value and average values of Co/Ni ratio of pyrite samples in different stages of Huaishuping gold deposit"

样品编号 成矿阶段 δFe δS Co Ni As Co/Ni
HSPDO6B06 中 0.479 -3.167 0.114 0.200 0.054 0.57
HSPDO6B11 早 1.368 -2.563 0.090 0.033 0.050 2.73
HSPDO6B12 早 2.513 -2.672 0.142 0.012 0.028 11.83
HSPDO6B13 早 2.012 -3.723 0.290 0.060 0.097 4.83
HSPD16B01 中 1.985 -3.315 0.070 0.120 0.026 0.58
HSPD18B01 中 2.592 -2.969 0.097 0.163 - 0.60
HSPD20B01 晚 1.364 -2.895 0.198 0.100 0.038 1.98

Fig.8

δFe-δS characteristics of pyrites in different ores of Huaishuping gold deposit （base map modified by reference[24]）"

Fig.9

Triangular diagram of Co，Ni and As mass fractions of different pyrites in Huaishuping gold deposit （modified by reference[25]）"

1 GuoBaojian，LiYongfeng，WangZhiguang，et al.Type，metallogenetic regularities，mineralization model and prospecting proposal in the Xiong’ershan district［J］.Geology and Exploration，2005，41（5）：43-47.
2 ZhangJ，ChenY J，PirajnoF，et al.Geology，C-H-O-S-Pb isotope systematics and geochronology of the Yindongpo gold deposit，Tongbai mountains，central China：Implication for ore genesis［J］.Ore Geology Reviews，2013，53：343-356.
3 ZhangJ，ChenYJ，YangY，et al.Lead isotope systematics of the Weishancheng Au-Ag belt，Tongbai mountains，central China：Implication for ore genesis［J］.International Geology Reviews，2011，53（5/6）：656-676.
4 陈衍景.造山型矿床、成矿模式及找矿潜力［J］.中国地质，2006，33：1181-1196.
ChenYanjing.Orogenic-type deposits and their metallogenic model and exploration potential［J］.Geology in China，2006，33：1181-1196.
5 范宏瑞，谢亦汉，王英兰.豫西上宫构造蚀变岩型金矿成矿过程中的流体—岩石反应［J］.岩石学报，1998，14（4）：529-541.
FanHongrui，XieYihan，WangYinglan.Fluid-rock interaction during mineralization of the Shanggong structure-controlled alteration-type gold deposit in western Henan Province，central China［J］.Acta Petrologica Sinica，1998，14（4）：529-541.
6 陈衍景，林治家，PirajnoF，等.东秦岭上宫金矿流体成矿作用：稳定同位素地球化学研究结果［J］.矿物岩石，2004，24（3）：13-21.
ChenYanjing，LinZhijia，PirajnoF，et al.Hydrothermal metallogeny of the Shanggong gold deposit，east Qinling：Study on the stable isotope geochemistry［J］.Journal of Mineralogy and Petrology，2004，24（3）：13-21.
7 高灶其，李云，梁黎春.河南省嵩县东湾金矿成矿地质特征及成因分析［J］.华南地质与矿产，2008（2）：31-36.
GaoZaoqi，LiYun，LiangLichun.Geological characteristics and genesis of Dongwan gold deposit in Song County，Henan Province［J］.Geology and Mineral Retrans-sources of South China，2008（2）：31-36.
8 庞振山，徐文超，周奇明，等.河南省嵩县萑香洼金矿矿床地球化学特征［J］.矿产与地质，2008，22（6）：481-491.
PangZhenshan，XuWenchao，ZhouQiming，et al.Geochemical characteristics of Huanxiangwa gold deposit，Henan Province［J］.Mineral Resources and Geology，2008，22（6）：481-491.
9 张木辰，李喜山，徐海安，等.试论河南省嵩县槐树坪金矿矿床成因及找矿方向［J］.采矿技术，2010，10（1）：83-88.
ZhangMuchen，LiXishan，XuHai’an，et al.Discussion on the genesis and prospecting direction of the Huaishuping gold deposit in Song County，Henan Province［J］.Mining Technology，2010，10（1）：83-88.
10 吴发富，龚庆杰，石建喜，等.熊耳山矿集区金矿控矿地质要素分析［J］.地质与勘探，2012，48（5）：865-875.
WuFafu，GongQingjie，ShiJianxi，et al.Ore-controlling geological factors of gold deposits in the Xiong’ershan region，western Henan Province［J］.Geology and Exploration，2012，48（5）：865-875.
11 DengJ，GongQ J，WangC M，et al.Sequence of Late Jurassic-Early Cretaceous magmatic-hydrothermal events in the Xiong’ershan region，central China：An overview with new zircon U-Pb geochronology data on quartz porphyries［J］.Journal of Asian Earth Sciences，2014，79：161-172.
12 王炯辉，陈良，苏蔷薇，等.河南省嵩县槐树坪金矿床地质、同位素地球化学特征与成矿作用［J］.矿床地质，2016，35（3）：524-538.
WangJionghui，ChenLiang，SuQiangwei，et al.Geology，isotopic geochemistry and metallogenesis of Huaishuping gold deposit in Songxian County，Henan Province［J］.Mineral Deposits，2016，35（3）：524-538.
13 徐红伟，杨九鼎，王国库.河南省嵩县槐树坪金矿成矿地质特征及成因分析［J］.河南理工大学学报，2009，28（6）：719-726.
XuHongwei，YangJiuding，WangGuoku.Metallogenetic feature and origin analysis of Huaishuping gold deposit of Song County in Henan［J］.Journal of Henan Polytechnic University，2009，28（6）：719-726.
14 彭丽娜，魏俊浩，孙晓雁，等.浙东南怀溪铜金矿床黄铁矿标型特征及其地质意义［J］.地质与勘探，2009，45（5）：577-587.
PengLina，WeiJunhao，SunXiaoyan，etal.Typomorphic characteristics of pyrites in the Huaixi copper-gold deposit，southeastern Zhejiang Province and its geological significance［J］.Geology and Exploration，2009，45（5）：577-587.
15 魏佳林，曹新志，王庆峰，等.新疆阿希金矿床黄铁矿标型特征及其地质意义［J］.地质科技情报，2011，30（5）：89-96.
WeiJialin，CaoXinzhi，WangQingfeng，et al.Typomorphic characteristics and geological significance of the pyrites from Axi gold deposit，Xinjiang，China［J］.Geological Science and Technology Information，2011，30（5）：89-96.
16 翟德高，刘家军，韩思宇，等.黑龙江三道湾子碲金矿床黄铁矿标型特征及矿床变化保存过程分析［J］.地质学报，2013，87（1）：81-90.
ZhaiDegao，LiuJiajun，HanSiyu，et al.Typomorphic characteristics of pyrite and processes of changes and preservation of the Sandaowanzi telluride-gold deposit in Heilongjiang Province［J］.Acta Geologica Sinica，2013，87（1）：81-90.
17 余文林，葛文胜，廖华，等.新疆西准噶尔提依尔金矿黄铁矿热电性与微量元素特征及其地质意义［J］.现代地质，2018（1）：66-76.
YuWenlin，GeWensheng，LiaoHua，et al.Thermoelectricity and trace element characteristics of pyrites from Tiyier gold deposit in west Junggar，Xinjiang and their geological significance［J］.Geoscience，2018（1）：66-76.
18 李逸凡，李洪奎，汤启云，等.山东旧店金矿黄铁矿标型特征及其地质意义［J］.黄金科学技术，2015，23（2）：45-50.
LiYifan，LiHongkui，TangQiyun，et al.Typomorphic characteristics and geological significance of pyrite in Jiudian gold deposit，Shandong Province［J］.Gold Science and Technology，2015，23（2）：45-50.
19 陶诗龙，赖健清，张建东，等.广西龙头山金矿床黄铁矿标型特征及其地质意义［J］.地质找矿论丛，2017，32（1）：33-41.
TaoShilong，LaiJianqing，ZhangJiandong，et al.Typomorphic features of pyrites from the Longtoushan gold deposit，Guangxi Province and the geological significance［J］.Contributions to Geology and Mineral Retrains-sources Research，2017，32（1）：33-41.
20 申俊峰，李胜荣，马广钢，等.玲珑金矿黄铁矿标型特征及其大纵深变化规律与找矿意义［J］.地学前缘，2013，20（3）：55-75.
ShenJunfeng，LiShengrong，MaGuanggang，et al.Typomorphic characteristics of pyrite from the Linglong gold deposit：Its vertical variation and prospecting significance［J］.Earth Science Frontiers，2013，20（3）：55-75.
21 ZhangJ，DengJ，ChenH Y，et al.LA-ICP-MS trace element analysis of pyrite from the Chang’an gold deposit，Sanjiang region，China：Implication for ore-forming process［J］.Gondwana Research，2014，26：557-575.
22 ZhangJ，LiL，Gilbert，et al.LA-ICP-MS and EPMA studies on the Fe-S-As minerals from the Jinlongshan gold deposit，Qinling Orogen，China：Implications for ore-forming processes［J］.Geological Journal，2014，49：482-500.
23 李永峰.豫西熊耳山地区中生代花岗岩类时空演化与钼（金）成矿作用［D］.北京：中国地质大学（北京），2005.
LiYongfeng.The Temporal-Spatial Evolution of Mesozoic Granitoids in Xiong’ershan Area and Their Relationship to Molybdenum-Gold Mineralization［D］.Beijing：China University of Geosciences（Beijing），2005.
24 严育通，李胜荣，贾宝剑，等.中国不同成因类型金矿床的黄铁矿成分标型特征及统计分析［J］.地学前缘，2012，19（4）：214-226.
YanYutong，LiShengrong，JiaBaojian，et al.Composition typomorphic characteristics and statistic analysis of pyrite in gold deposits of different genetic types［J］.Earth Science Frontiers，2012，19（4）：214-226.
25 宋学信，张景凯.中国各种成因黄铁矿的微量元素特征［J］.中国地质科学院矿床地质研究所所刊，1986（2）：166-175.
SongXuexin，ZhangJingkai.Minor elements in pyrites of various genetic types from China［J］.Bulletin of the Institute of Mineral Deposits Chinese Academy of Geological Sciences，1986（2）：166-175.
26 周起凤.胶东乳山英格庄金矿成因矿物学与深部远景研究［D］.北京：中国地质大学（北京），2010.
ZhouQifeng.Genetic Mineralogy and Deep Prospects of the Yinggezhuang Gold Deposit in Rushan County，Jiaodong［D］.Beijing：China University of Geosciences（Beijing），2010.
27 陈衍景，倪培，范宏瑞，等.不同类型热液金矿系统的流体包裹体特征［J］.矿物学报，2007，23（9）：2085-2108.
ChenYanjing，NiPei，FanHongrui，et al.Fluid inclusion characteristics of different types of hydrothermal gold deposit systems［J］.Acta Mineralogica Sinica，2007，23（9）：2085-2108.
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