img

Wechat

Adv. Search

Gold Science and Technology ›› 2018, Vol. 26 ›› Issue (2): 241-247.doi: 10.11872/j.issn.1005-2518.2018.02.241

Previous Articles     Next Articles

Experimental Study on Bacterial Oxidation-Cyanidation of a Complex Re-fractory Gold Mine in Gansu Province

SONG Yan 1,YANG Hongying 1,TONG Linlin 1,MA Pengcheng 2,JIN Zhenan 1   

  1. 1.School of Metallurgy,Northeastern University,Shenyang 110819,Liaoning,China;2.Zhaojin Mining Industry Co.,Ltd.,Zhaoyuan 265400,Shandong,China
  • Received:2017-07-11 Revised:2017-08-15 Online:2018-04-30 Published:2018-05-19

Abstract: Taking the complex refractory gold mine containing sulfur,arsenic,carbon and antimony in Gansu Province as the research object,we carried out bacterial oxidation-cyanidation experiment.Bacteria used in the leaching was HQ0211 which was a kind of mixed bacteria being able to grow normally in the system containing arsenic after a long time of domestication.During leaching of the concentrate,the effects of different pulp densities on bacterial oxidation were evaluated by measuring the pH value of solution,the electric potential value of solution,the density of Fe2+,the density of arsenic in solution.The results indicated that the mixed bacteria cultures HQ0211 showed good biooxidation performance for the complex refractory gold concentrate. After biooxidation,the maximum sulfur removal efficiency of 81.53%,arsenic removal efficiency of 86.88%,carbon removal efficiency of 58.32% and antimony removal efficiency of 40.56% were achieved in the presence of the HQ0211 mixed culture.Highest gold recovery of 98.65% was achieved by cyanidation after biooxidation,which increased by 40.56% comparing to the result from cyanidation of the untreated concentrate.

Key words: complex refractory gold concentrate, bacterial oxidation, cyanidation, bioleaching bacteria HQ0211, sulfur removal efficiency, arsenic removal efficiency, carbon removal efficiency, antimony removal efficiency
参考文献(References):

CLC Number: 

  • TF831


[1] 付丹,梅雪,张晖.黄金价格与通货膨胀相关性的实证分析[J].黄金,2009,30(1):4-7.
 Fu Dan,Mei Xue,Zhang Hui.Empirical analysis on the correlation between gold price and inflation[J].Gold,2009,30(1):4-7.
[2] 李鹏远.中国黄金供需预测及对策研究[D].北京:中国地质大学(北京),2015.
 Li Pengyuan.China’s Gold Supply and Demand Forecasting and Countermeasure Research[D].Beijing:China University of Geosciences (Beijing),2015.
[3] 周博敏,安丰玲.世界黄金生产现状及中国黄金工业发展的思考[J].黄金,2012,33(3):1-6.
 Zhou Bomin,An Fengling.Current situations of worldwide gold production and considerations on gold industry development in China[J].Gold,2012,33(3):1-6.
[4] 杨洪英,巩恩普,杨立.低品位双重难处理金矿石工艺矿物学及浸金影响因素[J].东北大学学报(自然科学版),2008,29(12):1742-1745.
 Yang Hongying,Gong Enpu,Yang Li.Process mineralogy of low-grade double refractory gold ore and influencing factor on gold leaching[J].Journal of Northeastern University(Natural Science),2008,29(12):1742-1745.
[5] 陈懋弘,毛景文,陈振宇,等.滇黔桂“金三角”卡林型金矿含砷黄铁矿和毒砂的矿物学研究[J].矿床地质,2009,28(5):539-557.
 Chen Maohong,Mao Jingwen,Chen Zhenyu,et al.Mineralogy of arsenian pyrites and arsenopyrites of carlin-type gold deposits in Yunnan-Guizhou-Guangxi “golden triangle” area,southwestern China[J].Mineral Deposits,2009,28(5):539-557.
[6] 张伟,王宏强,邓晓东,等.鄂东南地区鸡冠嘴铜金矿床Au-Ag-Bi-Te-Se矿物学研究与金银富集机理[J].岩石学报,2016,32(2):456-470.
 Zhang Wei,Wang Hongqiang,Deng Xiaodong,et al.Mineralogy of the Au-Ag-Bi-Te-Se assemblages in the Jiguanzui Cu-Au skarn deposit,Daye District,southeastern Hubei Province[J].Acta Petrologica Sinica,2016,32(2):456-470.
[7] 杨洪英,杨立,佟琳琳,等.广西金牙难浸金矿的工艺矿物学研究[J].东北大学学报(自然科学版),2007,28(8):1156-1158.
 Yang Hongying,Yang Li,Tong Linlin,et al.Process mineralogy of refractory gold ore in Jinya,Guangxi Province[J].Journal of Northeastern University (Natural Science),2007,28(8):1156-1158.
[8] 杨洪英,杨立,范有静,等.广西某难处理金矿金的赋存状态研究[J].贵金属,2003,24(4):32-35.
 Yang Hongying,Yang Li,Fan Youjing,et al.Study on gold occurrence state of refractory gold concentrates in Guangxi[J].Precious Metals,2003,24(4):32-35.
[9] 陈翠华,张燕,顾雪祥,等.贵州苗龙金矿床毒砂中金的赋存状态研究[J].矿床地质,2013,32(5):932-940.
 Chen Cuihua,Zhang Yan,Gu Xuexiang,et al.Modes of occurrence of gold in arsenopyrite from Miaolong gold deposit in Sandu,Guizhou Province[J].Mineral Deposits,2013,32(5):932-940.
[10] 张燕,陈翠华,顾雪祥,等.贵州三都苗龙金—锑矿床金赋存状态初步探讨[J].中国地质,2014,41(5):1620-1635.
 Zhang Yan,Chen Cuihua,Gu Xuexiang,et al.A preliminary study of modes of occurrence of gold in the Miaolong Au-Sb deposit of Sandu area,Guizhou Province[J].Geology in China,2014,41(5):1620-1635.
[11] Amankwah R K,Yen W T,Ramsay J A.A two-stage bacterial pretreatment process for double refractory gold ores[J].Minerals Engineering,2005,18(1):103-108.
[12] Song Y,Yang H Y,Tong L L.Bioleaching of complex refractory gold ore concentrate of China:Comparison of shake flask and continuous bioreactor[J].Advanced Materials Research,2015,1130:243-246.
[13] Liu Q,Yang H Y,Tong L L.Influence of Phanerochaete chrysosporium on degradation and preg-robbing capacity of activated carbon[J].Transactions of Nonferrous Metals Society of China,2014,24(6):1905-1911.
[14] Pan H D,Yang H Y,Tong L L,et al.Control method of chalcopyrite passivation in bioleaching[J].Transactions of Nonferrous Metals Society of China,2012,22(9):2255-2260.
[15] Liu Q,Yang H Y,Tong L L,et al.Fungal degradation of elemental carbon in Carbonaceous gold ore[J].Hydrometallurgy,2016,160(2):90-97.
[16] Chandraprabha M N,Modak J M,Natarajan K A,et al.Strategies for efficient start-up of continuous biooxidation process for refractory gold ores[J].Minerals Engineering,2002,15(10):751-753.
[17] Canales C,Acevedo F,Gentina J C.Laboratory-scale continuous bio-oxidation of a gold concentrate of high pyrite and enargite content[J].Process Biochemistry,2002,37(10):1051-1055.
[18] Lotfalian M,Ranjbar M,Fazaelipoor M H,et al.The effect of redox control on the continuous bioleaching of chalcopyrite concentrate[J].Minerals Engineering,2015,81:52-57.
[19] Elberling B,Schippers A,Sand W.Bacterial and chemical oxidation of pyritic mine tailings at low temperatures[J].Journal of Contaminant Hydrology,2000,41(3/4):225-238.
[20] Konishi Y,Kogasaki K,Asai S.Bioleaching of pyrite by Acidianus brierleyi in a continuous-flow stirred-tank reactor[J].Chemical Engineering Science,1997,52(24):4525-4532.
[21] Wei Y,Zhong K,Adamov E V,et al.Semi-continuous biooxidation of the Chongyang refractory gold ore[J].Minerals Engineering,1997,10(6):577-583.
[22] Brierley J A,Brierley C L.Present and future commercial applications of biohydrometallurgy[J].Process Metallurgy,1999,9(2):81-89.
[23] Ehrlich H L.Past,present and future of biohydrometallurgy[J].Hydrometallurgy,2001,59(2/3):127-134.

[1] Hefu LI,Hao SUN,Guohua YE,Xiaofeng QUE,Yawei WANG,Yang CHEN,Bin CHEN. Treatment of Xiajiadian Gold Mine with Environment-friendly Reagent Jinchan as a Substitute for Sodium Cyanide [J]. Gold Science and Technology, 2018, 26(5): 682-688.
[2] LI Jiafeng, YANG Hongying, TONG Linlin, JIN Zhenan, ZHANG Dengchao. Experimental Study on Bacterial Oxidation-Gold Extraction of Paodaoling Refractory Gold Concentrate [J]. Gold Science and Technology, 2018, 26(2): 248-253.
[3] CHEN Yajing,YANG Hongying,TONG Linlin,JIN Zhenan. Study on Arsenic Removal from Bacterial Oxidation of Liquid Arsenical Ores and Stability of Arsenic Calcium Residue [J]. Gold Science and Technology, 2018, 26(1): 124-129.
[4] CHEN Qiao,YANG Hongying,CHEN Guimin,TONG Linlin,NIU Huiqun. Application of Knelson Gravity Concentration in Quartz Vein Type Gold Beneficiation Process in China [J]. Gold Science and Technology, 2017, 25(5): 73-79.
[5] CHEN Shuibo,XIE Hongzhen,LAI Weiqiang,GUO Jinyi,YIN Han. Application of Gravity Separation and Cyanidation Combined Process on Certain Gold Ore in Xinjiang Province [J]. Gold Science and Technology, 2014, 22(6): 87-90.
[6] GAO Weiwei,LIU Jinqiang,LI Ruirui,ZHANG Rengao,DENG Hongrui,WANG Shanjian,LIN Xin. Application of Air-strength Agitation Leaching Trough in Gold Concentration Plant [J]. Gold Science and Technology, 2014, 22(3): 86-89.
[7] LAI Weiqiang,LIN Honghan,ZHANG Bo,YOU Manli. Experimental Research on Oxidized Refractory Gold Ore from Lintaolegai in Sumuna,Mongolia [J]. Gold Science and Technology, 2013, 21(5): 154-156.
[8] ZHONG Shuiping. Roasting-acid Leaching-cyanidation of Refractory Gold Concentrate Containing Copper [J]. Gold Science and Technology, 2013, 21(2): 82-85.
[9] XIE Hongzhen,HUANG Li,HUANG Huaiguo,LIN Honghan. Experimental Research on Pressurizing Oxidation-Cyanidation for a Copper Bearing Gold Concentrate [J]. Gold Science and Technology, 2013, 21(1): 89-93.
[10] XUE Guang,YU Yongjiang,LI Xian’en. Experimental Study of Cyanidation Leaching from Arsenic-Carbon Gold Ore [J]. Gold Science and Technology, 2012, 20(6): 56-57.
[11] ZHONG Weihua. Research on the Continuous Expanded Test of Flotation Gold Concentrate by Bacterial Oxidation-cyanide Leaching Method [J]. Gold Science and Technology, 2012, 20(6): 62-64.
[12] REN Hongsheng,XING Hongbo,LIU Xinyan,GUO Hong. Experimental Research on Bacterial Oxidation-Cyanide Leaching of Sandaogou Arsenic-bearing Gold Concentrate,Liaoning Province [J]. J4, 2012, 20(1): 78-81.
[13] GENG Hong-Bei, GUO Hong, LIN Hong-Qing. Experimental Research on Bacterial Oxidation-cyanide Leaching of Nancha Arsenic-bearing Gold Concentrate,Jilin Province [J]. J4, 2010, 18(1): 70-73.
[14] DUAN Liu-Tian, WANG Chi-Beng, WANG Gao-Tian, LI Chao-Qing. Study on Reclaiming of Gold from the Flotation Tailing Containg Arsenic and Cuprum of Chuantou Gold Deposit in Luoyang [J]. J4, 2009, 17(6): 63-65.
[15] XIAO Jing-Fei. Process and Practice of CIP Disposing the OriginalOre of Hetai Gold Deposit [J]. J4, 2009, 17(3): 64-67.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
[1] BAO Zhen-Xiang. [J]. Gold Science and Technology, 1994, 2(4): 29 -35 .
[2] LI Bin, JU Hai-Xiang, YANG Mu, DU Gao-Feng, HUI Ji-Kang, WANG Tian-Guo. [J]. J4, 2010, 18(4): 17 -21 .
[3] YAN Jie, QIN Ze-Li, XIE Wen-Bing, CA Bang-Yong. [J]. J4, 2010, 18(4): 22 -26 .
[4] LIN An-Zhi, DIAO Yu-Suo, XIAO Zhen, QING Min, WEI Feng, JIU Zhen-Beng. [J]. J4, 2010, 18(4): 27 -32 .
[5] YU Guang-Meng, BAI Mo-Cheng, GUO Dun-Hua. [J]. J4, 2010, 18(4): 33 -36 .
[6] LIU Dong-Hai, LIU Xin-Hui. Research on the Characteristics of Pyrite and its Gold -bearing Properties of Zhaishang Oversized Gold Deposit in Western Qinling[J]. J4, 2010, 18(6): 8 -12 .
[7] TUN Fu-Jiang, LIANG Qing-Ti. Research on Metallogenic Regularity of Boka Gold Deposit in Yunnan Province[J]. J4, 2011, 19(1): 1 -5 .
[8] ZHANG Chao, XIAO Xiao-Jiang. Geochemical Characteristics of Granite in Ningchanhe Area,North Qilian[J]. Gold Science and Technology, 2011, 19(1): 6 -10 .
[9] ZHANG Yan, SHANG Qian. Research Progress of Gold Deposits of Ductile Shear Zone——Taking Ailaoshan Gold Zone as an Example[J]. J4, 2011, 19(1): 11 -15 .
[10] HU Qin-Xia, CHEN Kai, CHEN Chao, ZHANG Ku-Xiao. Analysis on Geological Features and Metallogenic Regularities of Nacheng Silver Gold Deposit in Guangdong[J]. J4, 2011, 19(1): 16 -20 .