Research Progress on Removal of Cyanide in Water by Adsorption
Received date: 2022-04-22
Revised date: 2022-06-22
Online published: 2022-12-10
Cyanide in cyanide-containing wastewater is a highly toxic substance.Leakage of cyanide-containing wastewater into the environment will cause environmental pollution of water and soil and damage human health.cyanide into the organism will release cyanide ion （CN-），which will combine with the ferric iron oxidase in the mitochondria of cells，inhibit the reduction of ferric iron，hinder the normal respiration of cells，make cells lose the function of oxygen transfer，resulting in tissue hypoxia，leading to biological asphyxia and death. China has formulated strict standards for the discharge of cyanide wastewater.Therefore，it is necessary to carry out harmless treatment of cyanide-containing wastewater.Adsorption method is widely used in the treatment of cyanide-containing wastewater due to its advantages of simplicity，efficiency and economy.The widely used cyanide adsorption materials in the field of water treatment were reviewed，including carbonaceous adsorption materials，mineral materials，resin materials and new micro/nano materials，etc.The advantages and disadvantages of different adsorption materials in treating cyanide wastewater were compared.At the same time，the adsorption performance and mechanism of different adsorbents were discussed，mainly including the specific surface area of ??adsorbent materials，the treatment depth of cyanide，adsorption capacity，adsorption thermodynamics and kinetics.Adsorption mechanisms such as physical adsorption，chemical bonding，electrostatic attraction and ion exchange all occur in the adsorption of cyanide by adsorbent materials，such as activated carbon，zeolite，bentonite and other materials with rich pore structure for physical adsorption of cyanide.Metallic elements such as Cu，Zn，Fe and other metal elements in adsorbent materials can form metal complex cyanide chemical bond with CN- in the solution.The anion in the ion exchange resin，quaternary ammonium salt or nitrate modified material can occur ion exchange with cyanide.The research directions of cyanide adsorption materials in the future are prospected to provide reference for the development and application of cyanide adsorption materials，such as further development of easy access，large adsorption capacity，small desorption coefficient，recyclable，easy to recover，green and environmental protection，no secondary pollution，high selectivity adsorption materials.
Zuming NIE , Junhua TIAN , Zhongxian WU , Peiwei HAN , Jingmin YAN , Shufeng YE . Research Progress on Removal of Cyanide in Water by Adsorption[J]. Gold Science and Technology, 2022 , 30(5) : 797 -808 . DOI: 10.11872/j.issn.1005-2518.2022.05.056
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