收稿日期: 2024-05-30
修回日期: 2024-07-29
网络出版日期: 2024-09-19
基金资助
国家自然科学基金NSFC-山东省联合基金项目“胶东深部金矿断裂控矿机理”(U2006201);河北省人才项目“冀北地区金成矿系统及深部找矿技术”(HBQZYCXY0010)
Composition of Gold and Other Elements in the Mesozoic Magmatic Rocks of the Jiaodong Peninsula and Their Implications for Gold Mineralization
Received date: 2024-05-30
Revised date: 2024-07-29
Online published: 2024-09-19
胶东地区是我国最大的金成矿区，但是关于其巨量金的来源一直不明。通过对成矿前的晚侏罗世玲珑期岩体（玲珑、昆嵛山）、早白垩世早期郭家岭期岩体及其暗色包体（郭家岭、丛家）以及成矿后的早白垩世晚期伟德山型岩体及其暗色包体（崂山、牙山、艾山等）的Au、Cu和Ag等元素含量进行分析，发现这些亲铜元素相对于大陆地壳较为亏损。此外，玲珑期和伟德山期样品中Cu/Ag比值与Cu含量具有明显的正相关性。而郭家岭期岩体及其包体中以及伟德山期岩体中的暗色包体中，Cu/Ag比值与Au含量具有正相关性，表明在岩浆演化过程中，单硫化物固溶体从岩浆中持续分离，造成中生代岩浆岩具有较低的Cu/Ag比值和金属含量。这些硫化物的堆晶在中下地壳形成了富集Au等元素的矿源层，为胶东金成矿提供了物质基础。研究还表明，单硫化物固溶体分离是岩浆演化过程中普遍发育的现象，这种现象也可能是导致大陆地壳相对于地幔亏损Cu等元素的原因。
董磊磊 , 白鑫 , 宋明春 . 胶东中生代岩浆岩金等元素组成及其对金成矿的启示[J]. 黄金科学技术, 2024 , 32(5) : 768 -780 . DOI: 10.11872/j.issn.1005-518.2024.05.156
The Jiaodong Peninsula is the largest gold-producing region in China，however，the sources of its substantial gold reserves remains uncertain.Analyzing the trace elements in pre-mineralization Late Jurassic Linglong-type plutons （Linglong，Kunyushan），Early Cretaceous Guojialing-type plutons （Guojialing，Congjia），syn- to post-mineralization Early Cretaceous Weideshan-type plutons，and the mafic dioritic enclaves within the latter two plutons reveals that these formations generally exhibit lower concentrations of elements such as Cu，Au，Ag，Sb，and As compared to the average values of the continental crust.Specifically，the gold content is typically below 0.5×10-9，aligning with prior test results and suggesting a depletion process of elements such as gold during magmatic evolution.Furthermore，a significant positive correlation is observed between the Cu/Ag ratio and Cu content in both Linglong-type and Weideshan-type samples.In Guojialing-type plutons and their enclaves，a positive correlation between the Cu/Ag ratio and Au content has been observed.This relationship suggests that during magma evolution，monosulfide solid solution continuously separates from the magma.Consequently，Mesozoic magmatic rocks exhibit lower Cu/Ag ratios and reduced metal content.The accumulation of these sulfides in the middle to lower crust forms an enriched source layer of gold and other elements，thereby providing ore-forming materials essential for gold mineralization in the Jiaodong region.The study also suggests that the separation of monosulfide solid solutions during magma evolution may be a common process，which could also explain why the continental crust is depleted in copper and other elements compared to the mantle.
| null | Chen J F， Xie Z， Li H M，et al，2003.U-Pb zircon ages for a collision-related K-rich complex at Shidao in the Sulu ultrahigh pressure terrane，China［J］.Geochemical Journal，37：35-46. |
| null | Chen K， Tang M， Lee C T A，et al，2020.Sulfide-bearing cumulates in deep continental arcs：The missing copper reservoir［J］.Earth and Planetary Science Letters，531：115971. |
| null | Chen Yumin， Zeng Qingdong， Sun Zhifu，et al，2019.Study on geochemical background field of the gold deposits in Jiaodong，China［J］.Gold Science and Technology，27（6）：791-801. |
| null | Deng J， Wang Q F， Santosh M，et al，2020.Remobilization of metasomatized mantle lithosphere：A new model for the Jiaodong gold province，eastern China［J］.Mineralium Deposita，55：257-274. |
| null | Deng J， Wang Q F， Zhang L，et al，2023.Metallogenetic model of Jiaodong-type gold deposits，eastern China［J］.Science China Earth Sciences，66：2287-2310. |
| null | Dong L L， Yang Z M， Liu Y H，et al，2023a.Possible source of Au in the Jiaodong area from lower crustal sulfide cumulates：Evidence from oxygen states and chalcophile elements contents of Mesozoic magmatic suites［J］.Ore Geology Reviews，153：105268. |
| null | Dong L L， Yang Z M， Song M C，et al，2023b.Petrogenesis of Mesozoic Magmatic Suites in the Jiaodong Peninsula：Implications for crust-mantle interactions and decratonization［J］.Lithosphere，（1）：6226908. |
| null | Dong L L， Bai X， Song M C，et al，2023c.Crustal thickness of the Jiaodong Peninsula in the Mesozoic：Implications for the destruction of the North China Craton［J］.Frontiers in Earth Science，11：1171456. |
| null | Dong L L， Yang Z M， Bai X，et al，2023d.Generation of the Early Cretaceous granitoid in the Dazeshan region，Jiaodong Peninsula：Implications for the crustal reworking in the North China Craton［J］.Frontiers in Earth Science，10：1083608. |
| null | Faure M， Lin W， Le Breton N，2001.Where is the North China-South China boundary in eastern China［J］.Geology，29：119-122. |
| null | Gao Tianshan， Chen Jiangfeng， Xie Zhi，et al，2004.Geochemistry of Triassic igneous complex at Shidao in the Sulu UHP metamorphic belt［J］.Acta Petrologica Sinica，20（5）：1025-1038. |
| null | Goldfarb R J， Baker T， Dube B，et al，2005.Distribution，Chara-cter，and Genesis of Gold Deposits in Metamorphic Terra-nes［M］//Economic Geology 100th Anniversary Volume 40.Littleton：Society of Economic Geologists. |
| null | Goldfarb R J， Santosh M，2014.The dilemma of the Jiaodong gold deposits：Are they unique？［J］.Geoscience Frontiers，5：139-153. |
| null | Goss S C， Wilde S A， Wu F Y，et al，2010.The age，isotopic signature and significance of the youngest Mesozoic granitoids in the Jiaodong Terrane，Shandong Province，North China Craton［J］.Lithos，120：309-326. |
| null | Groves D I， Santosh M， Deng J，et al，2020.A holistic model for the origin of orogenic gold deposits and its implications for exploration［J］.Mineralium Deposita，55：275-292. |
| null | Guo Jinghui， Chen Fukun， Zhang Xiaoman，et al，2005.Evolution of syn- to post-collisional magmatism from north Sulu UHP belt，eastern China：Zircon U-Pb geochronology［J］.Acta Petrologica Sinica，21（4）：1281-1301. |
| null | Hou M L， Jiang Y H， Jiang S Y，et al，2007.Contrasting origins of late Mesozoic adakitic granitoids from the northwestern Jiaodong Peninsula，east China：Implications for crustal thickening to delamination［J］.Geological Magazine，144：619-631. |
| null | Jenner F E，2017.Cumulate causes for the low contents of sulfide-loving elements in the continental crust［J］.Nature Geoscience，10：524-529. |
| null | Jenner F E， Hauri E H， Bullock E S，et al，2015.The competing effects of sulfide saturation versus degassing on the behavior of the chalcophile elements during the differentiation of hydrous melts［J］.Geochemistry，Geophysics，Geosystems，16：1490-1507. |
| null | Jenner F E， O’neill H S C， Arculus R J，et al，2010.The magnetite crisis in the evolution of arc-related magmas and the initial concentration of Au，Ag and Cu［J］.Journal of Petrology，51：2445-2464. |
| null | Jenner F E， O’Neill H S C，2012.Analysis of 60 elements in 616 ocean floor basaltic glasses［J］.Geochemistry，Geophysics，Geosystems，13（2）：Q02005. |
| null | Jiang N， Chen J Z， Guo J H，et al，2012.In situ zircon U-Pb，oxygen and hafnium isotopic compositions of Jurassic granites from the North China craton：Evidence for Triassic subduction of continental crust and subsequent metamorphism-related 18O depletion［J］.Lithos，142：84-94. |
| null | Jiang P， Yang K F， Fan H R，et al，2016.Titanite-scale insights into multi-stage magma mixing in Early Cretaceous of NW Jiaodong terrane，North China Craton［J］.Lithos，258：197-214. |
| null | Li Z K， Li J W， Sun H，et al，2023a.Gold mineralized diorite beneath the Linglong ore field，North China Craton：New insights into the origin of decratonization-related gold deposits［J］.GSA Bulletin，136（1/2）：277-294. |
| null | Li J， Wang C W， Song M C，et al，2023b.Petrogenesis of the Laoshan Suite in the Jiaodong Peninsula （Eastern China）：An oxidized low Ba-Sr A1-type granite［J］.Minerals，13：1012. |
| null | Li Y， Audétat A，2012.Partitioning of V，Mn，Co，Ni，Cu，Zn，As，Mo，Ag，Sn，Sb，W，Au，Pb，and Bi between sulfide phases and hydrous basanite melt at upper mantle conditions［J］.Earth and Planetary Science Letters，355：327-340. |
| null | Liu Pinghua， Liu Fulai， Wang Fang，2015.P-T-t paths of the multiple metamorphic events of the Jiaobei terrane in the southeastern segment of the Jiao-Liao-Ji Belt （ JLJB），in the North China Craton：Impication for formation and evolution of the JLJB［J］.Acta Petrologica Sinica，31（10）：2889-2941. |
| null | Lu Lina， Fan Hongrui， Hu Fangfang，et al，2011.Emplacement depth of the Guojialing granodiorites from the northwestern Jiaodong Peninsula，eastern China：Evidences from hornblende thermobarometry and fluid inclusions.［J］.Acta Petrologica Sinica，27（5）：1521-1532. |
| null | Ma L， Jiang S Y， Dai B Z，et al，2013.Multiple sources for the origin of Late Jurassic Linglong adakitic granite in the Shandong Peninsula，eastern China：Zircon U-Pb geochronological，geochemical and Sr-Nd-Hf isotopic evidence［J］.Lithos，162：251-263. |
| null | Patten C， Barnes S J， Mathez E A，et al，2013.Partition coefficients of chalcophile elements between sulfide and silicate melts and the early crystallization history of sulfide liquid：LA-ICP-MS analysis of MORB sulfide droplets［J］.Chemical Geology，358：170-188. |
| null | Pettke T， Diamond L W， Villa I M，1999.Mesothermal gold veins and metamorphic devolatilization in the northwestern Alps：The temporal link［J］.Geology，27：641-644. |
| null | Phillips G N，1993.Metamorphic fluids and gold［J］.Mineralogical Magazine，57：365-374. |
| null | Phillips G N， Powell R，2010.Formation of gold deposits：A metamorphic devolatilization model［J］.Journal of Metamorphic Geology，28：689-718. |
| null | Qiu K F， Deng J， Laflamme C，et al，2023.Giant Mesozoic gold ores derived from subducted oceanic slab and overlying sediments［J］.Geochimica et Cosmochimica Acta，343：133-141. |
| null | Rudnick R L， Gao S，2014.Composition of the continental crust［J］.Treatise on Geochemistry，3：1-64. |
| null | Song M C， Deng J， Yi P H，et al，2014.The kiloton class Jiaojia gold deposit in eastern Shandong Province and its genesis［J］.Acta Geologica Sinica-English Edition，88：801-824. |
| null | Song M C， Li J， Yu X F，et al，2021.Metallogenic characteristics and tectonic setting of the Jiaodong gold deposit，China［J］.Solid Earth Sciences，6：385-405. |
| null | Song M C， Li S Z， Santosh M，et al，2015.Types，characteristics and metallogenesis of gold deposits in the Jiaodong Peninsula，Eastern North China Craton［J］.Ore Geology Revie-ws，65（3）：612-625. |
| null | Wan Y S， Song B A， Liu D Y，et al，2006.SHRIMP U-Pb zircon geochronology of Palaeoproterozoic metasedimentary rocks in the North China Craton：Evidence for a major Late Palaeoproterozoic tectonothermal event［J］.Precambrian Research，149：249-271. |
| null | Wan Yusheng， Dong Chunyan， Ren Peng，et al，2017.Spatial and temporal distribution，compositional characteristics and formation and evolution of Archean TTG rocks in the North China Craton：A synthesis［J］.Acta Petrologica Sinica，33（5）：1405-1419. |
| null | Wang L G， Qiu Y M， McNaughton N J，et al，1998.Constraints on crustal evolution and gold metallogeny in the Northwestern Jiaodong Peninsula，China，from SHRIMP U-Pb zircon studies of granitoids［J］.Ore Geology Reviews，13：275-291. |
| null | Wang Q F， Liu X F， Yin R S，et al，2023.Metasomatized mantle sources for orogenic gold deposits hosted in high-grade metamorphic rocks：Evidence from Hg isotopes［J］.Geology，52：115-119. |
| null | Wang X， Wang Z C， Cheng H，et al，2022.Gold endowment of the metasomatized lithospheric mantle for giant gold deposits：Insights from lamprophyre dykes［J］.Geochimica et Cosmochimica Acta，316：21-40. |
| null | Wang Z C， Becker H， Liu Y S，et al，2018.Constant Cu/Ag in upper mantle and oceanic crust：Implications for the role of cumulates during the formation of continental crust［J］.Earth and Planetary Science Letters，493：25-35. |
| null | Wang Z C， Cheng H， Zong K Q，et al，2020.Metasomatized lithospheric mantle for Mesozoic giant gold deposits in the North China Craton［J］.Geology，48：169-173. |
| null | Wang Z C， Xu Z， Cheng H，et al，2021.Precambrian metamorphic crustal basement cannot provide much gold to form giant gold deposits in the Jiaodong Peninsula，China［J］.Precambrian Research，354：106045. |
| null | Xiong L， Zhao X F， Wei J H，et al，2020.Linking Mesozoic lode gold deposits to metal-fertilized lower continental crust in the North China Craton：Evidence from Pb isotope systematics［J］.Chemical Geology，553：119440. |
| null | Xiong L， Zhao X F， Zhao S R，et al，2021.Formation of giant gold provinces by subduction-induced reactivation of fossilized，metasomatized continental lithospheric mantle in the North China Craton［J］.Chemical Geology，580：120362. |
| null | Yang Jinhui， Zhu Meifei， Liu Wei，et al，2003.Geochemistry and petrogenesis of Guojialing granodiorites from the northwestern Jiaodong Peninsula，eastern China［J］.Acta Petrologica Sinica，19（4）：692-700. |
| null | Yang K F， Fan H R， Santosh M，et al，2012.Reactivation of the Archean lower crust：Implications for zircon geochronology，elemental and Sr-Nd-Hf isotopic geochemistry of late Mesozoic granitoids from northwestern Jiaodong Terrane，the North China Craton［J］.Lithos，146/147：112-127. |
| null | Zeng Lingsen， Chen Jing， Chen Zhenyu，et al，2007.Emplacement depth of the Shidao granitic complex and the rapid exhumation of the Sulu ultrahigh pressure rocks：New constraints on the mechanisms for rapid exhumation［J］.Acta Petrologica Sinica，23（12）：3171-3179. |
| null | Zhang J， Zhao Z F， Zheng Y F，et al，2010.Postcollisional magmatism：Geochemical constraints on the petrogenesis of Mesozoic granitoids in the Sulu orogen，China［J］.Lithos，119：512-536. |
| null | Zhang Yueqiao， Li Jinliang， Zhang Tian，et al，2007.Late Mesozoic Kinematic History of the Muping-Jimo Fault Zone in Jiaodong Peninsula，Shandong Province，East China［J］.Geological Review，53（3）：289-300. |
| null | Zhao G V， Sun M， Wilde S A，et al，2005.Late Archean to Paleoproterozoic evolution of the North China Craton：Key issues revisited［J］.Precambrian Research，136：177-202. |
| null | Zhu Guang， Liu Cheng， Gu Chengchuan，et al，2018.Oceanic plate subduction history in the western Pacific Ocean：Constraint from late Mesozoic evolution of the Tan-Lu fault zone［J］.Science China Earth Sciences，48（4）：415-435. |
| null | 陈玉民，曾庆栋，孙之夫，等，2019.胶东金地球化学背景研究［J］.黄金科学技术，27（6）：791-801. |
| null | 高天山，陈江峰，谢智，等，2004.苏鲁超高压变质带中三叠纪石岛杂岩体的地球化学研究［J］.岩石学报，20（5）：1025-1038. |
| null | 郭敬辉，陈福坤，张晓曼，等，2005.苏鲁超高压带北部中生代岩浆侵入活动与同碰撞—碰撞后构造过程：锆石 U-Pb 年代学［J］.岩石学报，21（4）：1281-1301. |
| null | 刘平华，刘福来，王舫，2015.胶北地体多期变质事件的P-T-t轨迹及其对胶—辽—吉带形成与演化的制约［J］.岩石学报，31（10）：2889-2941. |
| null | 陆丽娜，范宏瑞，胡芳芳，等，2011.胶西北郭家岭花岗闪长岩侵位深度：来自角闪石温压计和流体包裹体的证据［J］.岩石学报，27（5）：1521-1532. |
| null | 万渝生，董春艳，任鹏，等，2017.华北克拉通太古宙TTG岩石的时空分布、组成特征及形成演化：综述［J］.岩石学报，33（5）：1405-1419. |
| null | 杨进辉，朱美妃，刘伟，等，2003.胶东地区郭家岭花岗闪长岩的地球化学特征及成因［J］.岩石学报，19（4）：692-700. |
| null | 曾令森，陈晶，陈振宇，等，2007.山东石岛花岗岩复合岩体的侵位深度与苏鲁超高压变质岩的快速折返机制及动力学效应［J］.岩石学报，23（12）：3171-3179. |
| null | 张岳桥，李金良，张田，等，2007.胶东半岛牟平—即墨断裂带晚中生代运动学转换历史［J］.地质论评，53（3）：289-300. |
| null | 朱光，刘程，顾承串，等，2018.郯庐断裂带晚中生代演化对西太平洋俯冲历史的指示［J］.中国科学：地球科学，48（4）：415-435. |
/
| 〈 |
|
〉 |
©2018 黄金科学技术编辑部
电话：0931-8277791
E-mail: hjkx@lzb.ac.cn 邮编：730000
甘公网安备 62010202000672号