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钱虎(1974-),男,安徽枞阳人,工程师,从事黄金选冶生产工艺技术研究工作。1380131@stu.neu.edu.cn |
收稿日期: 2022-12-19
修回日期: 2023-06-16
网络出版日期: 2023-09-20
基金资助
“十三五”固废资源化国家重点研发项目子课题“常规氰渣选冶联合无害化处置与全组份利用集成技术工程示范”(SQ2018YFC1902003)
Key Technology Research and Industrial Application of SART Process in the Treatment of Cyanide Gold Leaching Circulating Liquid
Received date: 2022-12-19
Revised date: 2023-06-16
Online published: 2023-09-20
为实现氰化循环液中有价金属的综合回收,通过开展酸化法与SART工艺(硫化—酸化—再循环—浓缩工艺)对比试验,最终确定采用SART工艺对国内黄金行业氰化提金过程中产生的循环液进行净化处理。通过开展SART工艺控制参数的试验研究,并应用于工业化生产,实现了氰化循环在液相中锌和铜的分步回收、分离沉淀,分别产出47.45%的锌泥和54.38%的铜泥,以高品位沉淀物产品加以回收,并将弱络合氰转化成游离NaCN再回到生产系统循环利用,从而降低氰化工艺的成本。SART工艺的应用,既实现了有价金属回收,降低了成本费用,又解决了劳动就业,减轻了后续冶炼及环保压力,取得了较好的经济、环境及社会效益。
钱虎 , 隋靖 , 赵艳玲 , 徐忠敏 . SART工艺处理氰化提金循环液的关键技术研究与产业化应用[J]. 黄金科学技术, 2023 , 31(4) : 698 -706 . DOI: 10.11872/j.issn.1005-2518.2023.04.183
In order to realize the comprehensive recovery of valuable metals in the cyanide circulating liquid,the comparative test and analysis of acidification and SART processes(Vulcanization-Acidification-Recycling-Concentration Process) was conducted,and the application of SART process was finally determined.Then the circulating liquid generated in the cyanide gold extraction process of the domestic gold industry was purified for the first time,and the step-by-step recovery and separation and precipitation of zinc and copper in the liquid phase of the cyanidation cycle were realized.47.45% zinc mud and 54.38% copper sludge were produced respectively,and recovered with high-grade precipitate products.And the weakly complexed cyanide is converted into free sodium cyanide and then returned to the production system for recycling,thereby reducing the cost of the cyanidation process.The application of SART process not only realizes the recovery of valuable metals,reduces the cost,but also solves the employment problem,reduces the pressure of subsequent smelting and environmental protection,and achieves good economic,environmental and social benefits.
Key words: SART process; cyanide circulating fluid; copper mud; zinc sludge; sodium cyanide
http://www.goldsci.ac.cn/article/2023/1005-2518/1005-2518-2023-31-4-698.shtml
|
China Gold Association,2017. Cyanide Copper Mud:T/C GA008-2017 [S].Beijing:China Gold Association.
|
China Gold Association,2021. Cyanide Zinc Mud:T/C GA028-2021 [S].Beijing:China Gold Association.
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
陈华进,李方实,2005.含氰废水处理方法进展[J].江苏化工,33(1):39-43.
|
高腾跃,刘奎仁,韩庆,等,2015.电沉积回收氰化尾液中铜和氰化物的研究[J].东北大学学报(自然科学版),36(1):81-85.
|
胡杨甲,贺政,赵志强,等,2018.非氰浸金技术发展现状及应用前景[J].黄金,39(4):53-58.
|
兰新哲,张聪惠,党晓娥,等,1999.提金氰化物回收循环再用技术新进展[J].黄金科学技术,7(3):40-45.
|
李骞,董斯宇,许瑞,等,2020.金矿提金技术及其研究进展[J].黄金,41(9):86-101.
|
李一凡,宋永辉,周民,等,2022.氰化提金废水中金属氰络合离子的溶剂萃取[J].中国有色金属学报,32(2):536-544.
|
牛桂强,2009.氰化工艺技术改造与生产实践[J].中国矿山工程,38(5):30-33.
|
钱新明,吕虹辉,郭向东,1997.树脂吸附尾液再利用的应用研究[J].黄金,18(6):51-53.
|
沈贤德,2014.酸化—硫化沉淀工艺处理紫金山金矿堆浸贵液工业调试及评价[J].黄金,35(11):76-80.
|
孙兆学,2011.贵金属生产技术实用手册[M].北京:冶金工业出版社.
|
谭希发,2014.酸化—硫化沉淀工艺处理紫金山金矿吸附贫液扩大试验研究[J].黄金,35(10):74-78.
|
王建政,孔令强,王敏杰,等,2021.氰化贫液脱除锌铜与循环浸出利用试验研究[J].黄金,42(5):79-81,86.
|
王倩儒,1994.合理利用贫液提高经济效益[J].矿产保护与利用,(5):45-48.
|
吴在玖,2013.高含铜氰化贫液处理工艺研究[J].有色冶金设计与研究,(3):18-20.
|
谢敏雄,李政要,孙文波,2010.氰化贫液除杂的必要性及其综合评估[J].黄金科学技术,18(6):73-77.
|
徐天允,徐正春,1985.金的氰化与冶炼[M].沈阳:沈阳黄金专科学校.
|
杨静,张亚莉,于先进,等,2012.氰化贫液处理方法研究现状[J].湿法冶金,31(5):278-280.
|
于先进,张亚莉,房涛,等,2014.离子交换法处理氰化贫液中铜的工艺及动力学[J].有色金属(冶炼部分),(5):8-11.
|
张曼曼,冯占立,王军强,等,2019.黄金湿法冶炼含氰废水处理研究进展[J].化学工业与工程,36(1):2-9.
|
仲崇波,王成功,陈炳辰,2001.氰化物的危害及其处理方法综述[J].金属矿山,6(5):44-47.
|
中国黄金协会,2017. 氰化铜泥:T/C GA008-2017 [S].北京:中国黄金协会.
|
中国黄金协会,2021. 氰化锌泥:T/C GA028-2021 [S].北京:中国黄金协会.
|
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