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关键金属矿产勘查进展专栏

滇黔桂地区不同成矿温度热液金矿床磷灰石矿物化学特征:兼论卡林型金成矿流体来源特殊性

  • 刘林林 , 1, 2 ,
  • 陈军 , 1, 2, 3 ,
  • 杨再风 1, 2 ,
  • 杜丽娟 1, 2, 3 ,
  • 吉彦冰 1, 2 ,
  • 郑禄林 4
展开
  • 1. 贵州大学资源与环境工程学院,贵州 贵阳 550025
  • 2. 贵州大学喀斯特地质资源与环境教育部重点实验室,贵州 贵阳 550025
  • 3. 矿床地球化学国家重点实验室,贵州 贵阳 550081
  • 4. 贵州大学矿业学院,贵州 贵阳 550025
陈军(1987-),男,甘肃定西人,副教授,从事低温热液矿床研究工作。

刘林林(1999-),男,贵州仁怀人,硕士研究生,从事矿物学、岩石学和矿床学研究工作。

收稿日期: 2022-09-30

  修回日期: 2022-11-28

  网络出版日期: 2023-04-27

基金资助

贵州省科技支撑计划(一般)项目“南盘江—右江地区多期构造/热液演化过程及其成矿效应研究”(编号:黔科合支撑[2023]一般112)、国家自然科学基金地区基金项目“硅化对右江盆地卡林型金矿成矿过程的制约:以泥堡金矿床为例”(41962008)

矿床地球化学国家重点实验室开放研究基金“贵州三都—丹寨成矿带Au-Sb-Hg成矿流体演化及对成矿过程的约束”(201905)

“右江盆地多期构造/热液演化对金—锑富集成矿的制约”(202210)

贵州大学培育项目“右江盆地低温热液矿集区金、锑多幕式成矿过程研究”(贵大培育[2020]7号)

Chemical Characteristics of Apatite Minerals in Hydrothermal Gold Deposits with Different Metallogenic Temperatures in the Yunnan-Guizhou-Guangxi Region:A Discussion on the Particularity of Sources of Ore-forming Fluids of the Carlin-type Gold Deposits

  • Linlin LIU , 1, 2 ,
  • Jun CHEN , 1, 2, 3 ,
  • Zaifeng YANG 1, 2 ,
  • Lijuan DU 1, 2, 3 ,
  • Yanbing JI 1, 2 ,
  • Lulin ZHENG 4
Expand
  • 1. College of Resource and Environmental Engineering, Guizhou University, Guiyang 550025, Guizhou, China
  • 2. Key Laboratory of Karst Georesources and Environment, Ministry of Education, Guizhou University, Guiyang 550025, Guizhou, China
  • 3. State Key Laboratory of Ore Deposit Geochemistry, Guiyang 550081, Guizhou, China
  • 4. Mining College of Guizhou University, Guiyang 550025, Guizhou, China

Received date: 2022-09-30

  Revised date: 2022-11-28

  Online published: 2023-04-27

本文亮点

滇—黔—桂地区是我国重要的金成矿区之一,分布有众多高温岩浆热液型金(铜)矿床和低温热液型金矿床,但这些矿床的成矿物质来源和形成过程仍存在争议。通过对高温岩浆—热液型金(铜)矿床(姚安金矿床和普朗金铜矿床)和低温卡林型金矿床(八渡和泥堡)中的热液磷灰石进行微量元素统计分析发现:高温富碱斑岩型金(铜)矿床中的磷灰石自形程度较好,具有较高的F和Cl含量,稀土元素呈轻稀土富集,重稀土亏损;相对而言,低温卡林型金矿床中产出的磷灰石自形程度较差,具有相对较低的F和Cl含量,稀土呈中稀土富集模式。另外,磷灰石δEu-δCe图解和球粒陨石标准化稀土元素配分模式揭示卡林型金矿床相对于岩浆热液型铜、金矿床具有更高的氧逸度。结合右江盆地辉锑矿稀土元素地球化学分析,认为磷灰石(包括萤石和方解石)中稀土(MREE)富集特征指示低温成矿流体可能与特殊的盆地基底岩石存在一定联系。综合分析认为:磷灰石在高温—中低温金矿床中具有独特的地球化学特征,能够有效揭示矿床类型及成矿流体演化过程。

本文引用格式

刘林林 , 陈军 , 杨再风 , 杜丽娟 , 吉彦冰 , 郑禄林 . 滇黔桂地区不同成矿温度热液金矿床磷灰石矿物化学特征:兼论卡林型金成矿流体来源特殊性[J]. 黄金科学技术, 2023 , 31(2) : 219 -231 . DOI: 10.11872/j.issn.1005-2518.2023.02.132

Highlights

Yunnan-Guizhou-Guangxi region,one of the most important gold mineralization areas in China,hosts many high temperature magmatic hydrothermal gold (copper) deposits,such as Pulang gold-bearing porphyry copper deposit,Beiya and Yaoan gold deposits,and low temperature hydrothermal gold deposits,namely carlin-type gold deposit,such as Badu,Nibao and Shuiyindong gold deposits.A lot of chemical studies of minerals,such as magnetite,pyrite and apatite have been carried out,and the abundant mineralogical geochemical data of trace elements in situ have been accumulated. However,the source materials and formation process of the deposits are still be disputed.Therefore,further statistical and comparative analyses of these data may provide a basis for revealing metallogenic information and guiding prospecting exploration.Due to the unique chemical characteristics,apatite can better preserve the important information of magma-hydrothermal evolution process,and is often used to define the fine metallogenic process of ore deposits.In this paper,the trace elements of hydrothermal apatite in high-temperature magma-hydrothermal deposits(Yao’an gold deposit and Pulang gold-bearing copper deposit) and low-temperature carlin-type gold deposits(Badu and Nibao gold deposits) have been collected and analyzed.It is found that the apatite in the high-temperature alkali-rich porphyry gold (copper) deposit is characterized by automorphic shape,high F and Cl contents,enriched LREE,and depleted HREE.In contrast,the apatite in the low-temperature carlin-type gold deposits is characterized by hypautomorphic and xenomorphic shapes,low F and Cl contents,enriched MREE.In addition,the δEu-δCe binary diagram and chondrite-normalized REE patterns revealed that the carlin-type gold deposits have higher oxygen fugacity than magmatic hydrothermal copper and gold deposits.Combined with the geochemical analysis of rare earth elements of stibnite in the Youjiang Basin,it is concluded that the enrichment characteristics of MREE in apatite(including fluorite and calcite) indicate that the low-temperature mineralizing fluid may be related to the special basin basement rock. In conclusion,apatite has unique geochemical characteristics in high temperature-medium and low temperature gold deposits,which can effectively reveal the type of ore deposit and the evolution process of ore-forming fluid.

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全球矿业投资迎来前所未有发展机遇

3月30日,第二届中国国际矿业投资与发展高峰会议在北京召开。本次会议聚焦“立足中国矿业·打造全球矿业发展共同体”,持续深入研判全球矿业发展趋势和初级矿产品产销贸形势,积极寻求国际矿业市场的增长潜力、合作空间和发展机遇,旨在助力矿业企业迎接新挑战、抓住新机遇,精准服务中国矿业企业参与国际矿业投资合作,推动矿业高质量发展。自然资源部中国地质调查局党组成员、副局长徐学义出席会议并致辞。

会议指出,矿产资源是经济社会发展的重要物质基础,我国统筹利用国内国际“两个市场、两种资源”,形成了国内国际双循环相互促进的新发展格局,深化国际矿业合作对于促进我国高质量发展、维护全球产业链供应链稳定具有重要意义。近年来,中国地质调查局积极服务“一带一路”倡议,深化全球矿产资源供需格局与利用布局研究,加强全球矿产资源潜力、开发条件、投资环境等综合评价,为国家能源资源安全保障和中资企业开展国际矿业合作提供了决策依据。同时,局国际矿业研究中心积极推动中非地学合作中心等国际地学中心建设,全力打造国际矿业投资与发展高峰会议等交流平台,为中国企业开展国际矿业投资合作提供了重要技术支撑和信息服务。

会议认为,当今世界正经历百年未有之大变局,全球能源资源供需版图深刻变革,错综复杂的国际局势对全球矿产资源稳定供应提出新的更高要求。受世界经济复苏乏力、通货膨胀加剧、能源危机全球蔓延等因素影响,能源和大宗商品供给等矛盾和问题愈发突出。同时,全球能源绿色低碳转型,高新技术、新材料和新能源产业的蓬勃发展促进矿产品需求结构发生显著变化,全球矿业投资与发展也将迎来前所未有的发展机遇。

在此背景下,要积极秉持合作共赢理念,共同维护国际矿业市场稳定、可持续发展;要共同推动完善全球矿业治理体系,全方位加强矿业合作;要加强科技合作交流,为矿业可持续发展提供新动能;要探索金融支持矿业发展的长效机制,完善矿业金融支持体系;要推进矿业领域ESG(环境、社会和公司治理)治理,推动矿业绿色高质量发展。

会上,相关专家围绕宏观经济与矿业形势、矿业投资市场分析与展望、矿产品投资分析等作主题发言,并围绕“复杂外部环境对矿企海外投资的影响”等话题开展深入讨论与交流。同时,会议期间,还举行了矿权信息路演及手册发布活动。

会议由“矿业界”主办,北京矿世科技有限公司、三匠会展公司联合承办。来自全国大型矿业企业、行业协会、研究机构、金融机构,以及地质(矿、勘)局等百余家单位的200余名代表参加会议。

脚注

http://www.goldsci.ac.cn/article/2023/1005-2518/1005-2518-2023-31-2-219.shtml

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